4-Chlorocrotonaldehyde as a unique chlorine-containing compound from the reaction of atomic chlorine with 1,3-Butadiene in air at room temperature

Geophysical Research Letters

Volumn 27, Issue 7, 2000, Pages 947-950

  Wang, W ^a   Finlayson Pitts, B J ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; CHLORINE; COASTAL ZONE; TROPOSPHERE;

ARCTIC VEHICLES; CHLORINE; COASTAL ZONES; TROPOSPHERE; ARCTIC ENGINEERING; BUTADIENE; CHLORINE COMPOUNDS; COASTAL ENGINEERING; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GAS CHROMATOGRAPHY; MASS SPECTROMETRY;

1 ,3-BUTADIENE; ATOMIC CHLORINE; CHLORINE ATOM; COASTAL AREA; IN-FIELD; MOTOR VEHICLE; PRODUCT STUDIES; TROPOSPHERIC CHEMISTRY;

CHLORINE COMPOUNDS; GEOPHYSICS;

CHLOROCROTONALDEHYDE;

EID: 0034353251     PISSN: 00948276     EISSN: None     Source Type: Journal    
DOI: 10.1029/1999GL011051     Document Type: Article

References (30)

1. Kinetics of gas-phase reactions of Cl atoms with chloroethenes at 298 ± 2 K and atmospheric pressure
2. Gas-phase tropospheric chemistry of volatile organic compounds: A review
3. Gas-phase tropospheric chemistry of volatile organic compounds, 1. Alkanes and alkenes
4. Production and decay of ClNO2 from the reaction of gaseous N2O5 with NaCl solution: Bulk and aerosol experiments
5. γ-Halogenation of α,β-unsaturated aldehydes
6. Rate coefficients for the gas-phase reactions of bromine radicals with a series of alkenes, dienes, and aromatic hydrocarbons at 298 ± 2 K
7. Heterogeneous chemistry in the troposphere: Experimental approaches and applications to the chemistry of sea salt particles
8. Emissions of benzene, toluene, xylenes and 1,3-butadiene from a representative portion of the Australian car fleet
9. Chlorine atoms as a potential tropospheric oxidant in the marine boundary layer
10. Tropospheric budget of reactive chlorine
11. Measurements of photolyzable chlorine and bromine during the Polar Sunrise Experiment 1995
12. Measurements of C2-C6 hydrocarbons during the Polar Sunrise 1992 Experiment
13. Formation and removal reactions of hazardous air pollutants
14. Measurement technique for inorganic chlorine gases in the marine boundary layer
15. Reactive chlorine: A potential sink for dimethylsulfide and hydrocarbons in the marine boundary layer
16. Concentrations and transformations of hazardous air pollutants
17. Thermal chlorine-38 atom reactions with ethylene
18. Unique products of the reaction of isoprene with atomic chlorine: Potential markers of Cl atom chemistry
19. Kinetics of Cl atom reactions with butadienes including isoprene
20. Evidence of inorganic chlorine gases other than hydrogen chloride in marine surface air
21. Kinetics and mechanism of the reaction of Cl atoms with 2-methyl-1,3-butadiene (isoprene) at 298 K
22. Low ozone in the marine boundary layer of the tropical pacific ocean - photochemical loss, chlorine atoms, and entrainment
23. Unexpectedly high concentrations of molecular chlorine in coastal air
24. Kinetics of the gas phase reaction of chlorine atoms with a series of alkenes, alkynes and aromatic species at 295 K
25. Hydrocarbon and halocarbon measurements as photochemical and dynamical indicators of atmospheric hydroxyl, atomic chlorine, and vertical mixing obtained during lagrangian flights
26. Tropospheric hydroxyl and atomic chlorine concentrations, and mixing timescales determined from hydrocarbon and halocarbon measurements made over the Southern Ocean
27. Evaporative emissions of 1,3-butadiene from petrol-fuelled motor vehicles