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Reactions that failed to show appreciable conversion ( < 10%) after 10 h trial reactions were considered to display negligible reactivity. It is possible, however, that some of these complexes are still effective catalysts for the ATRP of MMA but that they possess long induction periods or they react very slowly.
-
-
-
-
69
-
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0343384143
-
-
note
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Since in situ reactions with purified CuBr, 5, and xylenes in the absence of Cu(0) did proceed to an appreciable extent but with slightly broader molecular weight distributions (PDI ∼1.3), the lower reactivity is probably attributable to partial oxidation of Cu(I) during precomplexed catalyst preparation.
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0343384141
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2O purification. 17, 260, 15% conversion; PDIs ∼ 2.2-3.9).
-
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77
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0343819819
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note
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2 and EtOH.
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