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Volumn 32, Issue 1, 1999, Pages 27-35

Controlled radical polymerization of (meth)acrylates by ATRP with NiBr2(PPh3)2 as catalyst

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; BROMINE COMPOUNDS; CATALYSTS; COMPOSITION EFFECTS; FREE RADICAL POLYMERIZATION; INITIATORS (CHEMICAL); MOLECULAR WEIGHT DISTRIBUTION; MONOMERS; NICKEL COMPOUNDS; ORGANIC ACIDS; REACTION KINETICS; THERMODYNAMIC STABILITY;

EID: 0032759392     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma980995u     Document Type: Article
Times cited : (203)

References (61)
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    • See also: (d) Patten, T. E.; Xia, J.; Abernathy, T.; Matyjaszewski, K. Science 1996, 272, 866. (e) Matyjaszewski, K.; Patten, T. E.; Xia, J. J. Am. Chem. Soc. 1997, 119, 674. (f) Grimaud, T.; Matyjaszewski, K. Macromolecules 1997, 30, 2216.
    • (1996) Science , vol.272 , pp. 866
    • Patten, T.E.1    Xia, J.2    Abernathy, T.3    Matyjaszewski, K.4
  • 27
    • 0031040483 scopus 로고    scopus 로고
    • See also: (d) Patten, T. E.; Xia, J.; Abernathy, T.; Matyjaszewski, K. Science 1996, 272, 866. (e) Matyjaszewski, K.; Patten, T. E.; Xia, J. J. Am. Chem. Soc. 1997, 119, 674. (f) Grimaud, T.; Matyjaszewski, K. Macromolecules 1997, 30, 2216.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 674
    • Matyjaszewski, K.1    Patten, T.E.2    Xia, J.3
  • 28
    • 0031557566 scopus 로고    scopus 로고
    • See also: (d) Patten, T. E.; Xia, J.; Abernathy, T.; Matyjaszewski, K. Science 1996, 272, 866. (e) Matyjaszewski, K.; Patten, T. E.; Xia, J. J. Am. Chem. Soc. 1997, 119, 674. (f) Grimaud, T.; Matyjaszewski, K. Macromolecules 1997, 30, 2216.
    • (1997) Macromolecules , vol.30 , pp. 2216
    • Grimaud, T.1    Matyjaszewski, K.2
  • 33
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    • No catalyst degradation have been noticed even after 2 days in contact with air
    • No catalyst degradation have been noticed even after 2 days in contact with air.
  • 34
    • 0030715291 scopus 로고    scopus 로고
    • Sawamoto has recently studied the performance of differents initiators and demonstrated that the dimer of MMA end-capped by Br (dimethyl 2-bromo-2,4,4′-trimethylglutarate) was more efficient than the 2-ethylbromoisobutyrate. See: Ando, T.; Kamigaito, M.; Sawamoto, M. Tetrahedron 1997, 53 (45), 15445.
    • (1997) Tetrahedron , vol.53 , Issue.45 , pp. 15445
    • Ando, T.1    Kamigaito, M.2    Sawamoto, M.3
  • 37
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    • monomer x conversion
    • monomer x conversion.
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    • See for example: Gridnev, A. A. Macromolecules 1997, 30, 7651 and references therein.
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    • g was measured during the second heating run
    • g was measured during the second heating run.
  • 61
    • 18844434447 scopus 로고    scopus 로고
    • note
    • The temperature was first raised to 130°C for 30 min and then increased to 250°C (heating rate of 10°C/min) and maintained at that temperature for 6 h. All these steps were performed under nitrogen flow.


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