Metal-catalyzed oxidations, 10. New insights into the mechanism of hydroperoxide activation by investigation of dynamic processes in the coordination sphere of seven-coordinated molybdenum peroxo complexes

European Journal of Inorganic Chemistry

Volumn , Issue 5, 2000, Pages 1107-1114

  Hroch, Angelika ^a   Gemmecker, Gerd ^a   Thiel, Werner R ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

Catalysis; Densitiy functional theory; Epoxidation; Reaction mechanisms

Indexed keywords

CHELATION; CHEMICAL ACTIVATION; DISSOCIATION; EPOXIDATION; LIGANDS; MOLYBDENUM COMPOUNDS;

COORDINATION SPHERE; DENSITIY FUNCTIONAL THEORY; DYNAMIC PROCESS; FUNCTIONAL THEORY; HYDROPEROXIDES; METAL-CATALYZED OXIDATIONS; MOLYBDENUM PEROXO COMPLEXES; NITROGEN DONORS; PYRAZOLYLPYRIDINE; REACTION MECHANISM;

CATALYSIS;

CHELATE; COORDINATION COMPOUND; HYDROPEROXIDE; LIGAND; MOLYBDENUM COMPLEX; PYRAZOLE DERIVATIVE; PYRIDINE DERIVATIVE;

ARTICLE; CATALYSIS; COMPLEX FORMATION; DISSOCIATION; EPOXIDATION; ISOMERISM; LIGAND BINDING; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTUM CHEMISTRY; REACTION ANALYSIS; THERMODYNAMICS;

EID: 0034084915     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0682(200005)2000:5<1107::AID-EJIC1107>3.0.CO;2-E     Document Type: Article

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