Biomimetic construction of fused tricyclic ether by cascaded endo- cyclization of the hydroxy triepoxide

Synlett

Volumn , Issue 3, 2000, Pages 335-338

  Tokiwano, Tetsuo ^a   Fujiwara, Kenshu ^a   Murai, Akio ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

Biogenesis; Cascade cyclization; Hydroxy polyepoxides; Lanthanum(III) triflate; Polycyclic ethers

Indexed keywords

EPOXIDE; ETHER DERIVATIVE; LANTHANUM;

ARTICLE; CATALYSIS; CONFORMATIONAL TRANSITION; CYCLIZATION; REACTION ANALYSIS; SYNTHESIS;

EID: 0034052758     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

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56. -1.
57. 1H NMR.
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59. The corresponding chiral epoxidation of 12 under the similar conditions to the case of 17 led to formation of the chiral antidiepoxide (A) corresponding to 13a in an 83% isolated yield, though the absolute configuration is not able to be determined yet. (Equation presented) Scheme 6
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