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Volumn 39, Issue 8, 1998, Pages 833-836

Intramolecular addition of vinyl radicals to aldehydes

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; CYCLOHEXANOL; CYCLOPENTANOL; RADICAL; UNCLASSIFIED DRUG; VINYL DERIVATIVE;

EID: 0032546072     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)10743-2     Document Type: Article
Times cited : (31)

References (27)
  • 9
    • 0029990596 scopus 로고    scopus 로고
    • and references therein
    • 7) The fragmentation of alkoxy radicals has been used for the transfer of formyl groups, see : Jarreton, O.; Skrydstrup, T.; Beau, J. M. J. Chem. Soc., Chem. Commun. 1996, 1661-1662 and references therein.
    • (1996) J. Chem. Soc., Chem. Commun. , pp. 1661-1662
    • Jarreton, O.1    Skrydstrup, T.2    Beau, J.M.3
  • 11
    • 0028826606 scopus 로고
    • 9) Cyclizations of substituted 4-pentenyl-1-oxy radicals have been described recently, see : Hartung, J.; Gallou, F. J. Org. Chem. 1995, 60, 6706-6716.
    • (1995) J. Org. Chem. , vol.60 , pp. 6706-6716
    • Hartung, J.1    Gallou, F.2
  • 12
    • 0042789931 scopus 로고
    • 10) For a review, see : Dowd, P.; Zhang, W. Chem. Rev. 1993, 93, 2091-2115.
    • (1993) Chem. Rev. , vol.93 , pp. 2091-2115
    • Dowd, P.1    Zhang, W.2
  • 13
    • 0010663226 scopus 로고    scopus 로고
    • To the best of our knowledge, radical transesterifications involving alkoxy radicals have not been reported
    • 11) To the best of our knowledge, radical transesterifications involving alkoxy radicals have not been reported.
  • 16
    • 0010749589 scopus 로고    scopus 로고
    • note
    • 5: C, 57.89, H, 7.07. Found: C, 57.87, H, 7.15.
  • 17
    • 0010746323 scopus 로고    scopus 로고
    • note
    • 14) We can not yet completely rule away another minor pathway for 2, involving an O-ketyl radical, cyclizing in a 6-exo-trig mode followed by a bromide β-elimination.
  • 18
    • 0000030495 scopus 로고
    • 15) In comparison, the reaction of tin hydride with the analogous vinyl acceptor shows 83% of 6-exo-trig cyclization, 5% of 7-endo-trig, and 12% of 1,5-H transfer. See : Curran, D. P.; Shen, W. J. Am. Chem. Soc. 1993, 115, 6051-6059.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 6051-6059
    • Curran, D.P.1    Shen, W.2
  • 20
    • 0002234783 scopus 로고
    • 17) 5-endo-trig cyclizations involving all-carbon systems are quite rare, see for instance : a) Julia, M.; Le Goffic, F. Bull. Soc. Chim. Fr. 1965, 1550-1555
    • (1965) Bull. Soc. Chim. Fr. , pp. 1550-1555
    • Julia, M.1    Le Goffic, F.2
  • 24
    • 0010708377 scopus 로고    scopus 로고
    • note
    • 5: C, 56.07, H, 6.59. Found: C, 56.00, H, 6.65.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.