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Volumn 118, Issue 35, 1996, Pages 8395-8407

Comparison between SiMe2 and CMe2 spacers as σ-bridges for photoinduced charge transfer

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE; SILANE DERIVATIVE;

EID: 0029841920     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960546e     Document Type: Article
Times cited : (94)

References (95)
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    • Methylene-bridged donor-acceptor systems are already known to exhibit CT (intramolecular exciplex) emission. See for example: De Schryver, F. C.; Boens, N.; Put, J. Adv. Photochem. 1977, 10, 359. Okada, T.; Fujita, T.; Kubota, M.; Masaki, S.; Mataga, N.; Ide, R.; Sakata, Y.; Misumi, S. Chem. Phys. Lett. 1972, 14, 563-568. Ide, R.; Sakata, Y.; Misumi, S.; Okada, T.; Malaga, N. J. Chem. Soc., Chem. Commun. 1972, 1009-1011. CT emission of a methylene-bridged donor-donor'-acceptor compound has been reported as well: Masaki, Y.; Uehara, Y.; Yanagida, S.; Pac, C. Chem. Lett. 1992, 315-318.
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  • 29
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    • Methylene-bridged donor-acceptor systems are already known to exhibit CT (intramolecular exciplex) emission. See for example: De Schryver, F. C.; Boens, N.; Put, J. Adv. Photochem. 1977, 10, 359. Okada, T.; Fujita, T.; Kubota, M.; Masaki, S.; Mataga, N.; Ide, R.; Sakata, Y.; Misumi, S. Chem. Phys. Lett. 1972, 14, 563-568. Ide, R.; Sakata, Y.; Misumi, S.; Okada, T.; Malaga, N. J. Chem. Soc., Chem. Commun. 1972, 1009-1011. CT emission of a methylene-bridged donor-donor'-acceptor compound has been reported as well: Masaki, Y.; Uehara, Y.; Yanagida, S.; Pac, C. Chem. Lett. 1992, 315-318.
    • (1972) Chem. Phys. Lett. , vol.14 , pp. 563-568
    • Okada, T.1    Fujita, T.2    Kubota, M.3    Masaki, S.4    Mataga, N.5    Ide, R.6    Sakata, Y.7    Misumi, S.8
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    • Methylene-bridged donor-acceptor systems are already known to exhibit CT (intramolecular exciplex) emission. See for example: De Schryver, F. C.; Boens, N.; Put, J. Adv. Photochem. 1977, 10, 359. Okada, T.; Fujita, T.; Kubota, M.; Masaki, S.; Mataga, N.; Ide, R.; Sakata, Y.; Misumi, S. Chem. Phys. Lett. 1972, 14, 563-568. Ide, R.; Sakata, Y.; Misumi, S.; Okada, T.; Malaga, N. J. Chem. Soc., Chem. Commun. 1972, 1009-1011. CT emission of a methylene-bridged donor-donor'-acceptor compound has been reported as well: Masaki, Y.; Uehara, Y.; Yanagida, S.; Pac, C. Chem. Lett. 1992, 315-318.
    • (1972) J. Chem. Soc., Chem. Commun. , pp. 1009-1011
    • Ide, R.1    Sakata, Y.2    Misumi, S.3    Okada, T.4    Malaga, N.5
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    • 0343242458 scopus 로고
    • Methylene-bridged donor-acceptor systems are already known to exhibit CT (intramolecular exciplex) emission. See for example: De Schryver, F. C.; Boens, N.; Put, J. Adv. Photochem. 1977, 10, 359. Okada, T.; Fujita, T.; Kubota, M.; Masaki, S.; Mataga, N.; Ide, R.; Sakata, Y.; Misumi, S. Chem. Phys. Lett. 1972, 14, 563-568. Ide, R.; Sakata, Y.; Misumi, S.; Okada, T.; Malaga, N. J. Chem. Soc., Chem. Commun. 1972, 1009-1011. CT emission of a methylene-bridged donor-donor'-acceptor compound has been reported as well: Masaki, Y.; Uehara, Y.; Yanagida, S.; Pac, C. Chem. Lett. 1992, 315-318.
    • (1992) Chem. Lett. , pp. 315-318
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    • note
    • red(A) + C (compare with eq 3) the CT bands of the silanes should be red shifted to the CT bands of the diphenylpropanes. This discrepancy is in line with an earlier report (ref 47) on the unreliability of determining CT maxima by difference spectroscopy.
  • 58
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    • note
    • ∞. However, for the uncertain oxidation potential of 2C the value of the compound itself, +1.75 V, was used.
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    • Ph.D. Thesis, Delft University of Technology
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    • note
    • Very recently fitting procedures for a quantitative evaluation of V have been developed (ref 62). Unfortunately they cannot be reliably applied here because of the limited number of available data points. Application of the procedures, however, seems to establish that the coupling between ground and CT state is larger for 1C.
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    • -1.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.