Aliphatic hydroxylation by a bis(μ-oxo)dinickel(III) complex [3]

Journal of the American Chemical Society

Volumn 121, Issue 38, 1999, Pages 8945-8946

  Itoh, Shinobu ^a   Bandoh, Hideki ^a   Nagatomo, Shigenori ^b   Kitagawa, Teizo ^b   Fukuzumi, Shunichi ^a  

^a OSAKA UNIVERSITY   (Japan)

^b INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; ACETONITRILE; ALIPHATIC COMPOUND; COPPER COMPLEX; METHANOL; NICKEL COMPLEX; OXYGEN; SOLVENT; TRIETHYLAMINE;

ABSORPTION SPECTROSCOPY; CHEMICAL BOND; HYDROXYLATION; LETTER; LIGAND BINDING; RAMAN SPECTROMETRY; REACTION ANALYSIS; STOICHIOMETRY;

EID: 0033615272     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991326e     Document Type: Letter

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29. Experimental details about the synthesis and characterization of the bis(μ-hydroxo)dinickel(II) complexes, the product analysis, and the kinetics are deposited in Supporting Information.
30. See Supporting Information.
31. 2 concentration.
32. -1).
33. 4.
34. 19
35. 23
36. Rapid preequilibration of the bis(μ-oxo)dinickel(III) species with a small amount of the more reactive species could not be ruled out completely.