Modeling the Oxygen-Evolving Complex of Photosystem II. Synthesis, Redox Properties, and Core Interconversion Studies of Dimanganese Complexes Having {MnIII2(μ-O)(μ-OAc)2}2+, {MnIIIMnIV(μ-O)2(μ-OAc)}2+, and {MnIV2(μ-O)2(μ-OAc)}3+

Inorganic Chemistry

Volumn 37, Issue 10, 1998, Pages 2373-2382

  Lal, Tapan Kumar ^a   Mukherjee, Rabindranath ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY KANPUR   (India)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000476190     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971514a     Document Type: Article

References (94)

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19. Terminal tetradentate ligand coordination: (a) Arulsamy, N.; Glerup, J.; Hazell, A.; Hodgson, D. J.; McKenzie, C. J.; Toftlund, H. Inorg. Chem. 1994, 33, 3023. (b) Oberhausen, K. J.; O'Brien, R. J.; Richardson, J. F.; Buchanan, R. M.; Costa, R.; Latour, J.-M.; Tsai, H.-L.; Hendrickson, D. N. Inorg. Chem. 1993, 32, 4561.
20. Terminal tetradentate ligand coordination: (a) Arulsamy, N.; Glerup, J.; Hazell, A.; Hodgson, D. J.; McKenzie, C. J.; Toftlund, H. Inorg. Chem. 1994, 33, 3023. (b) Oberhausen, K. J.; O'Brien, R. J.; Richardson, J. F.; Buchanan, R. M.; Costa, R.; Latour, J.-M.; Tsai, H.-L.; Hendrickson, D. N. Inorg. Chem. 1993, 32, 4561.
21. Terminal tridentate ligand coordination: (a) Gultneh, Y.; Ahvaji, B.; Raja Khan, A.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chem. 1995, 34, 3633. (b) Wu, F.-J.; Kurtz, D. M., Jr.; Hagen, K. S.; Nyman, P. D.; Debrunner, P. G.; Vankai, V. A. Inorg. Chem. 1990, 29, 5174. (c) Toftlund, H.; Markiewicz, A.; Murray, K. S. Acta Chem. Scand. 1990, 44, 443. (d) Bossek, U.; Wieghardt, K.; Nuber, B.; Weiss, J. Inorg. Chim. Acta 1989, 165, 123. (e) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J.-J. J. Am. Chem. Soc. 1988, 110, 7398. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435. (g) Wieghardt, K.; Bossek, U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 1030. (h) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347.
22. Terminal tridentate ligand coordination: (a) Gultneh, Y.; Ahvaji, B.; Raja Khan, A.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chem. 1995, 34, 3633. (b) Wu, F.-J.; Kurtz, D. M., Jr.; Hagen, K. S.; Nyman, P. D.; Debrunner, P. G.; Vankai, V. A. Inorg. Chem. 1990, 29, 5174. (c) Toftlund, H.; Markiewicz, A.; Murray, K. S. Acta Chem. Scand. 1990, 44, 443. (d) Bossek, U.; Wieghardt, K.; Nuber, B.; Weiss, J. Inorg. Chim. Acta 1989, 165, 123. (e) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J.-J. J. Am. Chem. Soc. 1988, 110, 7398. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435. (g) Wieghardt, K.; Bossek, U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 1030. (h) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347.
23. Terminal tridentate ligand coordination: (a) Gultneh, Y.; Ahvaji, B.; Raja Khan, A.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chem. 1995, 34, 3633. (b) Wu, F.-J.; Kurtz, D. M., Jr.; Hagen, K. S.; Nyman, P. D.; Debrunner, P. G.; Vankai, V. A. Inorg. Chem. 1990, 29, 5174. (c) Toftlund, H.; Markiewicz, A.; Murray, K. S. Acta Chem. Scand. 1990, 44, 443. (d) Bossek, U.; Wieghardt, K.; Nuber, B.; Weiss, J. Inorg. Chim. Acta 1989, 165, 123. (e) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J.-J. J. Am. Chem. Soc. 1988, 110, 7398. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435. (g) Wieghardt, K.; Bossek, U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 1030. (h) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347.
24. Terminal tridentate ligand coordination: (a) Gultneh, Y.; Ahvaji, B.; Raja Khan, A.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chem. 1995, 34, 3633. (b) Wu, F.-J.; Kurtz, D. M., Jr.; Hagen, K. S.; Nyman, P. D.; Debrunner, P. G.; Vankai, V. A. Inorg. Chem. 1990, 29, 5174. (c) Toftlund, H.; Markiewicz, A.; Murray, K. S. Acta Chem. Scand. 1990, 44, 443. (d) Bossek, U.; Wieghardt, K.; Nuber, B.; Weiss, J. Inorg. Chim. Acta 1989, 165, 123. (e) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J.-J. J. Am. Chem. Soc. 1988, 110, 7398. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435. (g) Wieghardt, K.; Bossek, U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 1030. (h) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347.
25. Terminal tridentate ligand coordination: (a) Gultneh, Y.; Ahvaji, B.; Raja Khan, A.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chem. 1995, 34, 3633. (b) Wu, F.-J.; Kurtz, D. M., Jr.; Hagen, K. S.; Nyman, P. D.; Debrunner, P. G.; Vankai, V. A. Inorg. Chem. 1990, 29, 5174. (c) Toftlund, H.; Markiewicz, A.; Murray, K. S. Acta Chem. Scand. 1990, 44, 443. (d) Bossek, U.; Wieghardt, K.; Nuber, B.; Weiss, J. Inorg. Chim. Acta 1989, 165, 123. (e) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J.-J. J. Am. Chem. Soc. 1988, 110, 7398. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435. (g) Wieghardt, K.; Bossek, U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 1030. (h) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347.
26. Terminal tridentate ligand coordination: (a) Gultneh, Y.; Ahvaji, B.; Raja Khan, A.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chem. 1995, 34, 3633. (b) Wu, F.-J.; Kurtz, D. M., Jr.; Hagen, K. S.; Nyman, P. D.; Debrunner, P. G.; Vankai, V. A. Inorg. Chem. 1990, 29, 5174. (c) Toftlund, H.; Markiewicz, A.; Murray, K. S. Acta Chem. Scand. 1990, 44, 443. (d) Bossek, U.; Wieghardt, K.; Nuber, B.; Weiss, J. Inorg. Chim. Acta 1989, 165, 123. (e) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J.-J. J. Am. Chem. Soc. 1988, 110, 7398. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435. (g) Wieghardt, K.; Bossek, U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 1030. (h) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347.
27. Terminal tridentate ligand coordination: (a) Gultneh, Y.; Ahvaji, B.; Raja Khan, A.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chem. 1995, 34, 3633. (b) Wu, F.-J.; Kurtz, D. M., Jr.; Hagen, K. S.; Nyman, P. D.; Debrunner, P. G.; Vankai, V. A. Inorg. Chem. 1990, 29, 5174. (c) Toftlund, H.; Markiewicz, A.; Murray, K. S. Acta Chem. Scand. 1990, 44, 443. (d) Bossek, U.; Wieghardt, K.; Nuber, B.; Weiss, J. Inorg. Chim. Acta 1989, 165, 123. (e) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J.-J. J. Am. Chem. Soc. 1988, 110, 7398. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435. (g) Wieghardt, K.; Bossek, U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 1030. (h) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347.
28. Terminal tridentate ligand coordination: (a) Gultneh, Y.; Ahvaji, B.; Raja Khan, A.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chem. 1995, 34, 3633. (b) Wu, F.-J.; Kurtz, D. M., Jr.; Hagen, K. S.; Nyman, P. D.; Debrunner, P. G.; Vankai, V. A. Inorg. Chem. 1990, 29, 5174. (c) Toftlund, H.; Markiewicz, A.; Murray, K. S. Acta Chem. Scand. 1990, 44, 443. (d) Bossek, U.; Wieghardt, K.; Nuber, B.; Weiss, J. Inorg. Chim. Acta 1989, 165, 123. (e) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J.-J. J. Am. Chem. Soc. 1988, 110, 7398. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435. (g) Wieghardt, K.; Bossek, U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 1030. (h) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347.
29. Terminal bidentate and monodentate coordination: (a) Corbella, M.; Costa, R.; Ribas, J.; Fries, P. H.; Latour, J.-M.; Öhrströni, L.; Solans, X.; Rodríguez, V. Inorg. Chem. 1996, 35, 1857. (b) Reddy, K. R.; Rajasekharan; Sukumar, S. Polyhedron 1996, 15, 4161. (c) Vincent, J. B.; Tsai, H.-L.; Blackman, A. G.; Wang, S.; Boyd, P. D. W.; Folting, K.; Huffman, J. C.; Lobkovsky, E. B.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1993, 115, 12353. (d) Blackman, A. G.; Huffman, J. C.; Lobkovsky, E. B.; Christou, G. J. Chem. Soc., Chem. Commun. 1991, 989. (e) Ménage, S.; Girerd, J.-J.; Gleizes, A. J. Chem. Soc., Chem. Commun. 1988, 431.
30. Terminal bidentate and monodentate coordination: (a) Corbella, M.; Costa, R.; Ribas, J.; Fries, P. H.; Latour, J.-M.; Öhrströni, L.; Solans, X.; Rodríguez, V. Inorg. Chem. 1996, 35, 1857. (b) Reddy, K. R.; Rajasekharan; Sukumar, S. Polyhedron 1996, 15, 4161. (c) Vincent, J. B.; Tsai, H.-L.; Blackman, A. G.; Wang, S.; Boyd, P. D. W.; Folting, K.; Huffman, J. C.; Lobkovsky, E. B.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1993, 115, 12353. (d) Blackman, A. G.; Huffman, J. C.; Lobkovsky, E. B.; Christou, G. J. Chem. Soc., Chem. Commun. 1991, 989. (e) Ménage, S.; Girerd, J.-J.; Gleizes, A. J. Chem. Soc., Chem. Commun. 1988, 431.
31. Terminal bidentate and monodentate coordination: (a) Corbella, M.; Costa, R.; Ribas, J.; Fries, P. H.; Latour, J.-M.; Öhrströni, L.; Solans, X.; Rodríguez, V. Inorg. Chem. 1996, 35, 1857. (b) Reddy, K. R.; Rajasekharan; Sukumar, S. Polyhedron 1996, 15, 4161. (c) Vincent, J. B.; Tsai, H.-L.; Blackman, A. G.; Wang, S.; Boyd, P. D. W.; Folting, K.; Huffman, J. C.; Lobkovsky, E. B.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1993, 115, 12353. (d) Blackman, A. G.; Huffman, J. C.; Lobkovsky, E. B.; Christou, G. J. Chem. Soc., Chem. Commun. 1991, 989. (e) Ménage, S.; Girerd, J.-J.; Gleizes, A. J. Chem. Soc., Chem. Commun. 1988, 431.
32. Terminal bidentate and monodentate coordination: (a) Corbella, M.; Costa, R.; Ribas, J.; Fries, P. H.; Latour, J.-M.; Öhrströni, L.; Solans, X.; Rodríguez, V. Inorg. Chem. 1996, 35, 1857. (b) Reddy, K. R.; Rajasekharan; Sukumar, S. Polyhedron 1996, 15, 4161. (c) Vincent, J. B.; Tsai, H.-L.; Blackman, A. G.; Wang, S.; Boyd, P. D. W.; Folting, K.; Huffman, J. C.; Lobkovsky, E. B.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1993, 115, 12353. (d) Blackman, A. G.; Huffman, J. C.; Lobkovsky, E. B.; Christou, G. J. Chem. Soc., Chem. Commun. 1991, 989. (e) Ménage, S.; Girerd, J.-J.; Gleizes, A. J. Chem. Soc., Chem. Commun. 1988, 431.
33. Terminal bidentate and monodentate coordination: (a) Corbella, M.; Costa, R.; Ribas, J.; Fries, P. H.; Latour, J.-M.; Öhrströni, L.; Solans, X.; Rodríguez, V. Inorg. Chem. 1996, 35, 1857. (b) Reddy, K. R.; Rajasekharan; Sukumar, S. Polyhedron 1996, 15, 4161. (c) Vincent, J. B.; Tsai, H.-L.; Blackman, A. G.; Wang, S.; Boyd, P. D. W.; Folting, K.; Huffman, J. C.; Lobkovsky, E. B.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1993, 115, 12353. (d) Blackman, A. G.; Huffman, J. C.; Lobkovsky, E. B.; Christou, G. J. Chem. Soc., Chem. Commun. 1991, 989. (e) Ménage, S.; Girerd, J.-J.; Gleizes, A. J. Chem. Soc., Chem. Commun. 1988, 431.
34. Terminal asymmetric tridentate ligand coordination: (a) Mahapatra, S.; Lal, T. K.; Mukherjee, R. N. Inorg. Chem. 1994, 33, 1579. (b) Mahapatra, S.; Das, P.; Mukherjee, R. N. J. Chem. Soc., Dalton Trans. 1993, 215.
35. Terminal asymmetric tridentate ligand coordination: (a) Mahapatra, S.; Lal, T. K.; Mukherjee, R. N. Inorg. Chem. 1994, 33, 1579. (b) Mahapatra, S.; Das, P.; Mukherjee, R. N. J. Chem. Soc., Dalton Trans. 1993, 215.
36. Terminal tridentate ligand coordination: (a) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708 and references therein. (b) Pal, S.; Armstrong, W. H. Inorg. Chem. 1992, 31, 5417. (c) Pal, S.; Chan, M. K.; Armstrong, W. H. J. Am. Chem. Soc. 1992, 114, 6398. (d) Pal, S.; Gohdes, J. W.; Wilisch, W. C. A.; Armstrong, W. H. Inorg. Chem. 1992, 31, 713. (e) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G.; Blondin, G.; Girerd, J.-J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651.
37. Terminal tridentate ligand coordination: (a) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708 and references therein. (b) Pal, S.; Armstrong, W. H. Inorg. Chem. 1992, 31, 5417. (c) Pal, S.; Chan, M. K.; Armstrong, W. H. J. Am. Chem. Soc. 1992, 114, 6398. (d) Pal, S.; Gohdes, J. W.; Wilisch, W. C. A.; Armstrong, W. H. Inorg. Chem. 1992, 31, 713. (e) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G.; Blondin, G.; Girerd, J.-J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651.
38. Terminal tridentate ligand coordination: (a) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708 and references therein. (b) Pal, S.; Armstrong, W. H. Inorg. Chem. 1992, 31, 5417. (c) Pal, S.; Chan, M. K.; Armstrong, W. H. J. Am. Chem. Soc. 1992, 114, 6398. (d) Pal, S.; Gohdes, J. W.; Wilisch, W. C. A.; Armstrong, W. H. Inorg. Chem. 1992, 31, 713. (e) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G.; Blondin, G.; Girerd, J.-J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651.
39. Terminal tridentate ligand coordination: (a) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708 and references therein. (b) Pal, S.; Armstrong, W. H. Inorg. Chem. 1992, 31, 5417. (c) Pal, S.; Chan, M. K.; Armstrong, W. H. J. Am. Chem. Soc. 1992, 114, 6398. (d) Pal, S.; Gohdes, J. W.; Wilisch, W. C. A.; Armstrong, W. H. Inorg. Chem. 1992, 31, 713. (e) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G.; Blondin, G.; Girerd, J.-J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651.
40. Terminal tridentate ligand coordination: (a) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708 and references therein. (b) Pal, S.; Armstrong, W. H. Inorg. Chem. 1992, 31, 5417. (c) Pal, S.; Chan, M. K.; Armstrong, W. H. J. Am. Chem. Soc. 1992, 114, 6398. (d) Pal, S.; Gohdes, J. W.; Wilisch, W. C. A.; Armstrong, W. H. Inorg. Chem. 1992, 31, 713. (e) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G.; Blondin, G.; Girerd, J.-J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651.
41. One terminal tridentate and the other bidentate/monodentate ligand coordination: Bossek, U.; Saher, M.; Weyhermüller, T.; Wieghardt, K. J. Chem. Soc., Chem. Commun. 1992, 1780.
42. -/water ligand coordination: (a) Bashkin, J. S.; Schake, A. R.; Vincent, J. B.; Chang, H.-R.; Quioying, L.; Huffman, J. C. Christou, G.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1988, 700. (b) Reddy, K. R.; Rajasekharan, M. V.; Padhye, S.; Dahan, F.; Tuchagues, J.-P. Inorg. Chem. 1994, 33, 428. (c) Dave, B. C.; Czernuszewicz, R. S.; Bond, M. R. Carrano, C. J. Inorg. Chem. 1993, 32, 3593.
43. -/water ligand coordination: (a) Bashkin, J. S.; Schake, A. R.; Vincent, J. B.; Chang, H.-R.; Quioying, L.; Huffman, J. C. Christou, G.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1988, 700. (b) Reddy, K. R.; Rajasekharan, M. V.; Padhye, S.; Dahan, F.; Tuchagues, J.-P. Inorg. Chem. 1994, 33, 428. (c) Dave, B. C.; Czernuszewicz, R. S.; Bond, M. R. Carrano, C. J. Inorg. Chem. 1993, 32, 3593.
44. -/water ligand coordination: (a) Bashkin, J. S.; Schake, A. R.; Vincent, J. B.; Chang, H.-R.; Quioying, L.; Huffman, J. C. Christou, G.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1988, 700. (b) Reddy, K. R.; Rajasekharan, M. V.; Padhye, S.; Dahan, F.; Tuchagues, J.-P. Inorg. Chem. 1994, 33, 428. (c) Dave, B. C.; Czernuszewicz, R. S.; Bond, M. R. Carrano, C. J. Inorg. Chem. 1993, 32, 3593.
45. Terminal tetradentate ligand coordination: (a) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund, H. Inorg. Chem. 1994, 33, 4105. (b) Goodson, P. A.; Hodgson, D. J.; Glerup, J.; Michelsen, K.; Weihe, H. Inorg. Chim. Acta 1992, 197, 141. (c) Goodson, P. A.; Glerup, J.; Hodeson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (d) Goodson, P. A.; Hodgson, D. J.; Michelsen, K. Inorg. Chim. Acta 1990, 172, 49. (e) Goodson, P. A.; Oki. A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167.
46. Terminal tetradentate ligand coordination: (a) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund, H. Inorg. Chem. 1994, 33, 4105. (b) Goodson, P. A.; Hodgson, D. J.; Glerup, J.; Michelsen, K.; Weihe, H. Inorg. Chim. Acta 1992, 197, 141. (c) Goodson, P. A.; Glerup, J.; Hodeson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (d) Goodson, P. A.; Hodgson, D. J.; Michelsen, K. Inorg. Chim. Acta 1990, 172, 49. (e) Goodson, P. A.; Oki. A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167.
47. Terminal tetradentate ligand coordination: (a) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund, H. Inorg. Chem. 1994, 33, 4105. (b) Goodson, P. A.; Hodgson, D. J.; Glerup, J.; Michelsen, K.; Weihe, H. Inorg. Chim. Acta 1992, 197, 141. (c) Goodson, P. A.; Glerup, J.; Hodeson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (d) Goodson, P. A.; Hodgson, D. J.; Michelsen, K. Inorg. Chim. Acta 1990, 172, 49. (e) Goodson, P. A.; Oki. A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167.
48. Terminal tetradentate ligand coordination: (a) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund, H. Inorg. Chem. 1994, 33, 4105. (b) Goodson, P. A.; Hodgson, D. J.; Glerup, J.; Michelsen, K.; Weihe, H. Inorg. Chim. Acta 1992, 197, 141. (c) Goodson, P. A.; Glerup, J.; Hodeson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (d) Goodson, P. A.; Hodgson, D. J.; Michelsen, K. Inorg. Chim. Acta 1990, 172, 49. (e) Goodson, P. A.; Oki. A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167.
49. Terminal tetradentate ligand coordination: (a) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund, H. Inorg. Chem. 1994, 33, 4105. (b) Goodson, P. A.; Hodgson, D. J.; Glerup, J.; Michelsen, K.; Weihe, H. Inorg. Chim. Acta 1992, 197, 141. (c) Goodson, P. A.; Glerup, J.; Hodeson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (d) Goodson, P. A.; Hodgson, D. J.; Michelsen, K. Inorg. Chim. Acta 1990, 172, 49. (e) Goodson, P. A.; Oki. A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167.
50. Terminal tetradentate ligand coordination: (a) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund, H. Inorg. Chem. 1994, 33, 4105. (b) Goodson, P. A.; Hodgson, D. J.; Glerup, J.; Michelsen, K.; Weihe, H. Inorg. Chim. Acta 1992, 197, 141. (c) Goodson, P. A.; Glerup, J.; Hodeson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (d) Goodson, P. A.; Hodgson, D. J.; Michelsen, K. Inorg. Chim. Acta 1990, 172, 49. (e) Goodson, P. A.; Oki. A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167.
51. Terminal tetradentate ligand coordination: (a) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund, H. Inorg. Chem. 1994, 33, 4105. (b) Goodson, P. A.; Hodgson, D. J.; Glerup, J.; Michelsen, K.; Weihe, H. Inorg. Chim. Acta 1992, 197, 141. (c) Goodson, P. A.; Glerup, J.; Hodeson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (d) Goodson, P. A.; Hodgson, D. J.; Michelsen, K. Inorg. Chim. Acta 1990, 172, 49. (e) Goodson, P. A.; Oki. A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167.
52. Terminal tetradentate ligand coordination: (a) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund, H. Inorg. Chem. 1994, 33, 4105. (b) Goodson, P. A.; Hodgson, D. J.; Glerup, J.; Michelsen, K.; Weihe, H. Inorg. Chim. Acta 1992, 197, 141. (c) Goodson, P. A.; Glerup, J.; Hodeson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (d) Goodson, P. A.; Hodgson, D. J.; Michelsen, K. Inorg. Chim. Acta 1990, 172, 49. (e) Goodson, P. A.; Oki. A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167.
53. Terminal tetradentate ligand coordination: (a) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 1989, 28, 4446. (b) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967. (c) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763. (d) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477.
54. Terminal tetradentate ligand coordination: (a) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 1989, 28, 4446. (b) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967. (c) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763. (d) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477.
55. Terminal tetradentate ligand coordination: (a) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 1989, 28, 4446. (b) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967. (c) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763. (d) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477.
56. Terminal tetradentate ligand coordination: (a) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 1989, 28, 4446. (b) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967. (c) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763. (d) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477.
57. Terminal two bidentate ligand coordination: (a) Manchanda, R.; Brudvig, G. W.; Gala, S. de; Crabtree, R. H. Inorg. Chem. 1994, 33, 5157 and references therein. (b) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4743. (d) Cooper, S. R.; Dismukes, G. C.; Klein, M. P. J. Am. Chem. Soc. 1978, 100, 7248. (e) Cooper, S. R.; Calvin, M. J. Am. Chem. Soc. 1977, 99, 6623. (f) Plaksin, P. M.; Stouter, R. C.; Mathew, M.; Palenik, G. J. J. Am. Chem. Soc. 1972, 94, 2121.
58. Terminal two bidentate ligand coordination: (a) Manchanda, R.; Brudvig, G. W.; Gala, S. de; Crabtree, R. H. Inorg. Chem. 1994, 33, 5157 and references therein. (b) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4743. (d) Cooper, S. R.; Dismukes, G. C.; Klein, M. P. J. Am. Chem. Soc. 1978, 100, 7248. (e) Cooper, S. R.; Calvin, M. J. Am. Chem. Soc. 1977, 99, 6623. (f) Plaksin, P. M.; Stouter, R. C.; Mathew, M.; Palenik, G. J. J. Am. Chem. Soc. 1972, 94, 2121.
59. Terminal two bidentate ligand coordination: (a) Manchanda, R.; Brudvig, G. W.; Gala, S. de; Crabtree, R. H. Inorg. Chem. 1994, 33, 5157 and references therein. (b) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4743. (d) Cooper, S. R.; Dismukes, G. C.; Klein, M. P. J. Am. Chem. Soc. 1978, 100, 7248. (e) Cooper, S. R.; Calvin, M. J. Am. Chem. Soc. 1977, 99, 6623. (f) Plaksin, P. M.; Stouter, R. C.; Mathew, M.; Palenik, G. J. J. Am. Chem. Soc. 1972, 94, 2121.
60. Terminal two bidentate ligand coordination: (a) Manchanda, R.; Brudvig, G. W.; Gala, S. de; Crabtree, R. H. Inorg. Chem. 1994, 33, 5157 and references therein. (b) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4743. (d) Cooper, S. R.; Dismukes, G. C.; Klein, M. P. J. Am. Chem. Soc. 1978, 100, 7248. (e) Cooper, S. R.; Calvin, M. J. Am. Chem. Soc. 1977, 99, 6623. (f) Plaksin, P. M.; Stouter, R. C.; Mathew, M.; Palenik, G. J. J. Am. Chem. Soc. 1972, 94, 2121.
61. Terminal two bidentate ligand coordination: (a) Manchanda, R.; Brudvig, G. W.; Gala, S. de; Crabtree, R. H. Inorg. Chem. 1994, 33, 5157 and references therein. (b) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4743. (d) Cooper, S. R.; Dismukes, G. C.; Klein, M. P. J. Am. Chem. Soc. 1978, 100, 7248. (e) Cooper, S. R.; Calvin, M. J. Am. Chem. Soc. 1977, 99, 6623. (f) Plaksin, P. M.; Stouter, R. C.; Mathew, M.; Palenik, G. J. J. Am. Chem. Soc. 1972, 94, 2121.
62. Terminal tridentate ligand coordination: Kitajima, N.; Singh, U. P.; Amagai, H.; Osawa, M.; Moro-oka, Y. J. Am. Chem. Soc. 1991, 113, 7757.
63. Terminal tetradentate ligand coordination: Larson, E.; Lah, M. S.; Li, X.; Bonadies, J. A.; Pecoraro, V. L. Inorg. Chem. 1992, 31, 373.
64. (a) Gamelin, D. R.; Kirk, M. L.; Stemmler, T. L.; Pal, S.; Armstrong, W. H.; Penner-Hahn, J. E.; Solomon, E. I. J. Am. Chem. Soc. 1994, 116, 2392.
65. (b) Kirk, M. L.; Chan, M. K.; Armstrong, W. H.; Solomon, E. I. J. Am. Chem. Soc. 1992, 114, 10432.
66. 3tacn as the terminal ligand: Bossek, U.; Weyhermüller, T.; Wieghardt, K.; Nuber, B.; Weiss, J. J. Am. Chem. Soc. 1990, 112, 6387.
67. 2+ core: Bossek, U.; Hummel, H.; Weyhermüller, T.; Wieghardt, K.; Russell, S.; van der Wolf, L.; Kolb, U. Angew. Chem., Int. Ed. Engl. 1996, 35, 1552.
68. (a) Manchanda, R.; Thorp, H. H.; Brudvig, G. W.; Crabtree, R. H. Inorg. Chem. 1992, 31, 4040.
69. (b) Manchanda, R.; Thorp, H. H.; Brudvig, G. W.; Crabtree, R. H. Inorg. Chem. 1991, 30, 494.
70. (c) Thorp, H. H.; Sameski, J. E.; Brudvig, G. W.; Crabtree, R. H. J. Am. Chem. Soc. 1989, 111, 9249.
71. Manchanda, R.; Brudvig, G. W.; Crabtree, R. H.; Sarneski, J. E.; Didiuk, M. Inorg. Chim. Acta 1993, 212, 135.
72. 25
73. (a) Wemple, M. W.; Tsai, H.-L.; Folting, K.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1993, 32, 2025.
74. (b) Hendrickson, D. N.; Christou, G.; Schmitt, E. A.; Libby, E.; Bashkin, J. S.; Wang, S.; Tsai, H.-L.; Vincent, J. B.; Boyd, P. D. W.; Huffman, J. C.; Folting, K.; Li, Q.; Streib, W. E. J. Am. Chem. Soc. 1992, 114, 2455.
75. (c) Wang, S.; Tsai, H.-L.; Streib, W. E.; Christou, G.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1992, 1427.
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77. (a) Mahapatra, S.; Gupta, N.; Mukherjee, R. N. J. Chem. Soc., Dalton Trans. 1992, 3041.
78. (b) Gupta, N.; Mukerjee, S.; Mahapatra, S.; Ray, M.; Mukherjee, R. N. Inorg. Chem. 1992, 31, 139.
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82. O'Connor, C. J. Prog. Inorg. Chem. 1982, 29, 203.
83. Evans, D. F. J. Chem. Soc. 1959, 2003.
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86. 2+ core is clearly observable in the difference Fourier map. The asymmetric unit contains two such dimeric units, and one of the axial ligands for each Mn(III) center is provided by methylpyridyl moiety, as has been observed for 1b.
87. 2 complex 3 suitable for X-ray structural analysis.
88. III complex, for any possible ligand oxidation or degradation, are being planned.
89. The light colored filtrate of our reaction mixture exhibits the characteristic six-line EPR spectrum of manganese(II). Hence the unisolated manganese remains in the +2 oxidation level.
90. (a) Philouze, C.; Blondin, G.; Girerd, J.-J.; Guilhem, J.; Pascard, C.; Lexa, D. J. Am. Chem. Soc. 1994, 116, 8557.
91. (b) Sarneski, J. E.; Brzezinski, L. J.; Anderson, B.; Didiuk, M.; Manchanda, R.; Crabtree, R. H.; Brudvig, G. W.; Schulte, G. K. Inorg. Chem. 1993, 32, 3265.
92. (c) Sarneski, J. E.; Thorp, H. H.; Brudvig, G. W.; Crabtree, R. H.; Schulte, G. K. J. Am. Chem. Soc. 1990, 112, 7255.
93. 2O.
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