Synthesis and characterization of a hypervalent tellurium cation, Ph5Te+: A stable nonclassical onium compound [13]

Journal of the American Chemical Society

Volumn 121, Issue 46, 1999, Pages 10852-10853

  Minoura, Mao ^a   Mukuda, Takahiro ^a   Sagami, Takao ^a   Akiba, Kin Ya ^a  

^a HIROSHIMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CATION; TELLURIUM DERIVATIVE;

CHEMICAL STRUCTURE; LETTER; NONHUMAN; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; THERMODYNAMICS; X RAY CRYSTALLOGRAPHY;

EID: 0033601094     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja992828v     Document Type: Letter

References (46)

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18. For hypervalent organochalcogen reviews, see: Lunazzi, L.; Martin, J. C. In Organic Sulfur Chemistry; Bernardi, F., Csizmadia, I. G., Mangini, A., Eds.; Elsevier: Amsterdam, 1985; pp 408-483; Bergman, J.; Engman, L.; Sidén, L. In The Chemistry of Organic Selenium and Tellurium Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: New York, 1986; Vol. 1, pp 517-558; Detty, M. R.; O'Regan, M. B. In Tellurium-Containing Heterocycles; Taylor, E. C., Ed.; John Wiley & Sons: New York, 1994; pp 425-490; Furukawa, N.; Sato, S. In Rodd's Chemistry of Carbon Compounds: Sainsbury, M., Ed.; Elsevier: Amsterdam, 1996; Vol. IIIA, pp 469-520.
19. For hypervalent organochalcogen reviews, see: Lunazzi, L.; Martin, J. C. In Organic Sulfur Chemistry; Bernardi, F., Csizmadia, I. G., Mangini, A., Eds.; Elsevier: Amsterdam, 1985; pp 408-483; Bergman, J.; Engman, L.; Sidén, L. In The Chemistry of Organic Selenium and Tellurium Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: New York, 1986; Vol. 1, pp 517-558; Detty, M. R.; O'Regan, M. B. In Tellurium-Containing Heterocycles; Taylor, E. C., Ed.; John Wiley & Sons: New York, 1994; pp 425-490; Furukawa, N.; Sato, S. In Rodd's Chemistry of Carbon Compounds: Sainsbury, M., Ed.; Elsevier: Amsterdam, 1996; Vol. IIIA, pp 469-520.
20. For hypervalent organochalcogen reviews, see: Lunazzi, L.; Martin, J. C. In Organic Sulfur Chemistry; Bernardi, F., Csizmadia, I. G., Mangini, A., Eds.; Elsevier: Amsterdam, 1985; pp 408-483; Bergman, J.; Engman, L.; Sidén, L. In The Chemistry of Organic Selenium and Tellurium Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: New York, 1986; Vol. 1, pp 517-558; Detty, M. R.; O'Regan, M. B. In Tellurium-Containing Heterocycles; Taylor, E. C., Ed.; John Wiley & Sons: New York, 1994; pp 425-490; Furukawa, N.; Sato, S. In Rodd's Chemistry of Carbon Compounds: Sainsbury, M., Ed.; Elsevier: Amsterdam, 1996; Vol. IIIA, pp 469-520.
21. For hypervalent organochalcogen reviews, see: Lunazzi, L.; Martin, J. C. In Organic Sulfur Chemistry; Bernardi, F., Csizmadia, I. G., Mangini, A., Eds.; Elsevier: Amsterdam, 1985; pp 408-483; Bergman, J.; Engman, L.; Sidén, L. In The Chemistry of Organic Selenium and Tellurium Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: New York, 1986; Vol. 1, pp 517-558; Detty, M. R.; O'Regan, M. B. In Tellurium-Containing Heterocycles; Taylor, E. C., Ed.; John Wiley & Sons: New York, 1994; pp 425-490; Furukawa, N.; Sato, S. In Rodd's Chemistry of Carbon Compounds: Sainsbury, M., Ed.; Elsevier: Amsterdam, 1996; Vol. IIIA, pp 469-520.
22. 6-tellanylium, and we call this hypervalent telluronium in this report.
23. 6-tellanylium, and we call this hypervalent telluronium in this report.
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27. max (ε) 235 (36, 000), 275 (7, 500), 315 (2, 100).
28. w = 0.105) and GOF = 1.14 for 6442 observed reflections (685 parameters) with I > 3.00σ(I).
29. 2 in ref 5.
30. 2 in ref 5.
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