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note
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The absolute rale measurements are only accurate to ±30% due to uncertainties in the total pressure measurements. For the fastest reaction in eq 4, the efficiency of 0.38 could be from 0.26 to 0.50, corresponding to activation energies in the range -8.7 kcal/mol to barrierless (-18 kcal/mol). A 30% variation in an efficiency of 0.10, however, only corresponds to an uncertainty in activation energy of around ±1 kcal/mol.
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