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Volumn 121, Issue 50, 1999, Pages 11790-11797

Translational energy dependence and potential energy surfaces of gas phase S(N)2 and addition-elimination reactions

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; CHEMICAL REACTION KINETICS; ENERGY; GAS; MATHEMATICAL ANALYSIS; MOLECULAR INTERACTION; REACTION ANALYSIS;

EID: 0033596339     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja990556q     Document Type: Article
Times cited : (21)

References (72)
  • 20
    • 0027971670 scopus 로고
    • Hase, W. L. Science 1994, 266, 998-1002.
    • (1994) Science , vol.266 , pp. 998-1002
    • Hase, W.L.1
  • 37
    • 0343664997 scopus 로고
    • Ph.D. Dissertation, Stanford University
    • Wilbur, J. L. Ph.D. Dissertation, Stanford University, 1993.
    • (1993)
    • Wilbur, J.L.1
  • 68
    • 0342794801 scopus 로고    scopus 로고
    • Personal communication
    • Wang, H.; Hase, W. L. Personal communication.
    • Wang, H.1    Hase, W.L.2
  • 71
    • 0343664986 scopus 로고    scopus 로고
    • note
    • The absolute rale measurements are only accurate to ±30% due to uncertainties in the total pressure measurements. For the fastest reaction in eq 4, the efficiency of 0.38 could be from 0.26 to 0.50, corresponding to activation energies in the range -8.7 kcal/mol to barrierless (-18 kcal/mol). A 30% variation in an efficiency of 0.10, however, only corresponds to an uncertainty in activation energy of around ±1 kcal/mol.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.