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K. A. Boering, J. Rolfe, J. I. Brauman, Rapid Commun. Mass Spectrom. 6, 303 (1992); Int. J. Mass Spectrom. Ion Processes 117, 357 (1992).
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3
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1842393158
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note
-
There is a slight off-resonance effect on the nonresonant ions (3), but it is negligible at these powers and frequencies.
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5
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0021375586
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G. Caldwell, T. F. Magnera, P. Kebarle, J. Am. Chem. Soc. 106, 959 (1984); T. F. Magnera and P. Kebarle, in Ionic Processes in the Gas Phase, M. A. Almoster Ferreira, Ed. (Reidel, Dordrecht, Netherlands, 1984), vol. 118, pp. 135-157.
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M. A. Almoster Ferreira, Ed. Reidel, Dordrecht, Netherlands
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G. Caldwell, T. F. Magnera, P. Kebarle, J. Am. Chem. Soc. 106, 959 (1984); T. F. Magnera and P. Kebarle, in Ionic Processes in the Gas Phase, M. A. Almoster Ferreira, Ed. (Reidel, Dordrecht, Netherlands, 1984), vol. 118, pp. 135-157.
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1142278753
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R. A. Marcus, ibid. 20, 359 (1952); _, W. L. Hase, K. N. Swamy, J. Phys. Chem. 88, 6717 (1984); W. Forst, Theory of Unimolecular Reactions (Academic Press, New York, 1973); R. G. Gilbert and S. C. Smith, Theory of Unimolecular and Recombination Reactions, J. P. Simons, Ed. (Physical Chemistry Texts, Blackwell Scientific, Oxford, 1990); P. J. Robinson and K. A. Holbrook, Unimolecular Reactions (Interscience, London, 1972).
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J. P. Simons, Ed. Physical Chemistry Texts, Blackwell Scientific, Oxford
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R. A. Marcus, ibid. 20, 359 (1952); _, W. L. Hase, K. N. Swamy, J. Phys. Chem. 88, 6717 (1984); W. Forst, Theory of Unimolecular Reactions (Academic Press, New York, 1973); R. G. Gilbert and S. C. Smith, Theory of Unimolecular and Recombination Reactions, J. P. Simons, Ed. (Physical Chemistry Texts, Blackwell Scientific, Oxford, 1990); P. J. Robinson and K. A. Holbrook, Unimolecular Reactions (Interscience, London, 1972).
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1142278753
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Interscience, London
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R. A. Marcus, ibid. 20, 359 (1952); _, W. L. Hase, K. N. Swamy, J. Phys. Chem. 88, 6717 (1984); W. Forst, Theory of Unimolecular Reactions (Academic Press, New York, 1973); R. G. Gilbert and S. C. Smith, Theory of Unimolecular and Recombination Reactions, J. P. Simons, Ed. (Physical Chemistry Texts, Blackwell Scientific, Oxford, 1990); P. J. Robinson and K. A. Holbrook, Unimolecular Reactions (Interscience, London, 1972).
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Unimolecular Reactions
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Robinson, P.J.1
Holbrook, K.A.2
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18
-
-
1842277551
-
-
note
-
For a given translational energy, the center-of-mass collision energy in excess of the thermal value (0.045 eV at 350 K) is converted to an increased temperature of the reactants. Orbital angular momentum is conserved, and the increased fixed rotational energy is calculated from a classical collision model. The collision rate is calculated according to (70), and branching in the collision complex is then treated microcanonically (9) at the increased temperature.
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19
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0027971670
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W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
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Wang, H.1
Hase, W.L.2
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34
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1842283381
-
-
note
-
Earlier investigation of the translational energy dependence of Eq. 1 (6) did not cover a large enough energy range to be conclusive.
-
-
-
-
36
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0012459682
-
-
Standard Reference Database 19B, National Institute of Standards and Technology, Gaithersburg, MD
-
J. E. Bartmess, NIST Negative Ion Energetics Database, Version 3.0 (Standard Reference Database 19B, National Institute of Standards and Technology, Gaithersburg, MD, 1993).
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(1993)
NIST Negative Ion Energetics Database, Version 3.0
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-
Bartmess, J.E.1
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37
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1842399954
-
-
note
-
Supported by NSF. S.L.C. was supported by an NSF predoctoral fellowship, an American Chemical Society Division of Organic Chemistry DuPont Merck Pharmaceutical Fellowship, and a John Stauffer Memorial Fellowship.
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