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Volumn 276, Issue 5318, 1997, Pages 1536-1538

Perturbed equilibria and statistical energy redistribution in a gas- phase S(N)2 reaction

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; ENERGY METABOLISM; EQUILIBRIUM CONSTANT; GAS TRANSPORT; PRIORITY JOURNAL; STATISTICAL ANALYSIS; TRANSLATION REGULATION;

EID: 0031006046     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.276.5318.1536     Document Type: Article
Times cited : (44)

References (37)
  • 2
    • 0000048711 scopus 로고
    • K. A. Boering, J. Rolfe, J. I. Brauman, Rapid Commun. Mass Spectrom. 6, 303 (1992); Int. J. Mass Spectrom. Ion Processes 117, 357 (1992).
    • (1992) Int. J. Mass Spectrom. Ion Processes , vol.117 , pp. 357
  • 3
    • 1842393158 scopus 로고    scopus 로고
    • note
    • There is a slight off-resonance effect on the nonresonant ions (3), but it is negligible at these powers and frequencies.
  • 5
    • 0021375586 scopus 로고
    • G. Caldwell, T. F. Magnera, P. Kebarle, J. Am. Chem. Soc. 106, 959 (1984); T. F. Magnera and P. Kebarle, in Ionic Processes in the Gas Phase, M. A. Almoster Ferreira, Ed. (Reidel, Dordrecht, Netherlands, 1984), vol. 118, pp. 135-157.
    • (1984) J. Am. Chem. Soc. , vol.106 , pp. 959
    • Caldwell, G.1    Magnera, T.F.2    Kebarle, P.3
  • 6
    • 0002274785 scopus 로고
    • M. A. Almoster Ferreira, Ed. Reidel, Dordrecht, Netherlands
    • G. Caldwell, T. F. Magnera, P. Kebarle, J. Am. Chem. Soc. 106, 959 (1984); T. F. Magnera and P. Kebarle, in Ionic Processes in the Gas Phase, M. A. Almoster Ferreira, Ed. (Reidel, Dordrecht, Netherlands, 1984), vol. 118, pp. 135-157.
    • (1984) Ionic Processes in the Gas Phase , vol.118 , pp. 135-157
    • Magnera, T.F.1    Kebarle, P.2
  • 13
    • 1142278753 scopus 로고
    • R. A. Marcus, ibid. 20, 359 (1952); _, W. L. Hase, K. N. Swamy, J. Phys. Chem. 88, 6717 (1984); W. Forst, Theory of Unimolecular Reactions (Academic Press, New York, 1973); R. G. Gilbert and S. C. Smith, Theory of Unimolecular and Recombination Reactions, J. P. Simons, Ed. (Physical Chemistry Texts, Blackwell Scientific, Oxford, 1990); P. J. Robinson and K. A. Holbrook, Unimolecular Reactions (Interscience, London, 1972).
    • (1952) J. Chem. Phys. , vol.20 , pp. 359
    • Marcus, R.A.1
  • 14
    • 1142278753 scopus 로고
    • R. A. Marcus, ibid. 20, 359 (1952); _, W. L. Hase, K. N. Swamy, J. Phys. Chem. 88, 6717 (1984); W. Forst, Theory of Unimolecular Reactions (Academic Press, New York, 1973); R. G. Gilbert and S. C. Smith, Theory of Unimolecular and Recombination Reactions, J. P. Simons, Ed. (Physical Chemistry Texts, Blackwell Scientific, Oxford, 1990); P. J. Robinson and K. A. Holbrook, Unimolecular Reactions (Interscience, London, 1972).
    • (1984) J. Phys. Chem. , vol.88 , pp. 6717
    • Hase, W.L.1    Swamy, K.N.2
  • 15
    • 1142278753 scopus 로고
    • Academic Press, New York
    • R. A. Marcus, ibid. 20, 359 (1952); _, W. L. Hase, K. N. Swamy, J. Phys. Chem. 88, 6717 (1984); W. Forst, Theory of Unimolecular Reactions (Academic Press, New York, 1973); R. G. Gilbert and S. C. Smith, Theory of Unimolecular and Recombination Reactions, J. P. Simons, Ed. (Physical Chemistry Texts, Blackwell Scientific, Oxford, 1990); P. J. Robinson and K. A. Holbrook, Unimolecular Reactions (Interscience, London, 1972).
    • (1973) Theory of Unimolecular Reactions
    • Forst, W.1
  • 16
    • 1142278753 scopus 로고
    • J. P. Simons, Ed. Physical Chemistry Texts, Blackwell Scientific, Oxford
    • R. A. Marcus, ibid. 20, 359 (1952); _, W. L. Hase, K. N. Swamy, J. Phys. Chem. 88, 6717 (1984); W. Forst, Theory of Unimolecular Reactions (Academic Press, New York, 1973); R. G. Gilbert and S. C. Smith, Theory of Unimolecular and Recombination Reactions, J. P. Simons, Ed. (Physical Chemistry Texts, Blackwell Scientific, Oxford, 1990); P. J. Robinson and K. A. Holbrook, Unimolecular Reactions (Interscience, London, 1972).
    • (1990) Theory of Unimolecular and Recombination Reactions
    • Gilbert, R.G.1    Smith, S.C.2
  • 17
    • 1142278753 scopus 로고
    • Interscience, London
    • R. A. Marcus, ibid. 20, 359 (1952); _, W. L. Hase, K. N. Swamy, J. Phys. Chem. 88, 6717 (1984); W. Forst, Theory of Unimolecular Reactions (Academic Press, New York, 1973); R. G. Gilbert and S. C. Smith, Theory of Unimolecular and Recombination Reactions, J. P. Simons, Ed. (Physical Chemistry Texts, Blackwell Scientific, Oxford, 1990); P. J. Robinson and K. A. Holbrook, Unimolecular Reactions (Interscience, London, 1972).
    • (1972) Unimolecular Reactions
    • Robinson, P.J.1    Holbrook, K.A.2
  • 18
    • 1842277551 scopus 로고    scopus 로고
    • note
    • For a given translational energy, the center-of-mass collision energy in excess of the thermal value (0.045 eV at 350 K) is converted to an increased temperature of the reactants. Orbital angular momentum is conserved, and the increased fixed rotational energy is calculated from a classical collision model. The collision rate is calculated according to (70), and branching in the collision complex is then treated microcanonically (9) at the increased temperature.
  • 19
    • 0027971670 scopus 로고    scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1994) Science , vol.266 , pp. 998
    • Hase, W.L.1
  • 20
    • 0002339132 scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1986) Chem. Phys. Lett. , vol.129 , pp. 71
    • Basilevsky, M.V.1    Ryaboy, V.M.2
  • 21
    • 0001713888 scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1989) Chem. Phys. Lett. , vol.159 , pp. 371
    • Ryaboy, V.M.1
  • 22
    • 8344281148 scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1989) J. Am. Chem. Soc. , vol.111 , pp. 2349
    • Vande Linde, S.R.1    Hase, W.L.2
  • 23
    • 30844469815 scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1990) J. Phys. Chem. , vol.94 , pp. 6148
  • 24
    • 0027971670 scopus 로고    scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • J. Phys. Chem. , pp. 2778
  • 25
    • 0000817101 scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1990) J. Chem. Phys. , vol.93 , pp. 7962
  • 26
    • 0000606384 scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1992) J. Chem. Phys. , vol.96 , pp. 8275
    • Cho, Y.J.1    Vande Linde, S.R.2    Zhu, L.3    Hase, W.L.4
  • 27
    • 0001438409 scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 9644
    • Wang, H.1    Peslherbe, G.H.2    Hase, W.L.3
  • 28
    • 4243394015 scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1995) J. Chem. Phys. , vol.102 , pp. 5626
    • Peslherbe, G.H.1    Wang, H.2    Hase, W.L.3
  • 29
    • 0001325770 scopus 로고    scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1996) J. Phys. Chem. , vol.100 , pp. 19227
    • Viggiano, A.A.1    Morris, R.A.2
  • 30
    • 0030504943 scopus 로고    scopus 로고
    • W. L. Hase, Science 266, 998 (1994); M. V. Basilevsky and V. M. Ryaboy, Chem. Phys. Lett. 129, 71 (1986); V. M. Ryaboy, ibid. 159, 371 (1989); S. R. Vande Linde and W. L. Hase, J. Am. Chem. Soc. 111, 2349 (1989); J. Phys. Chem. 94, 6148 (1990); ibid., p. 2778; J. Chem. Phys. 93, 7962 (1990); Y. J. Cho, S. R. Vande Linde, L. Zhu, W. L. Hase, ibid. 96, 8275 (1992); H. Wang, G. H. Peslherbe, W. L. Hase, J. Am. Chem. Soc. 116, 9644 (1994); G. H. Peslherbe, H. Wang, W. L. Hase, J. Chem. Phys. 102, 5626 (1995); A. A. Viggiano and R. A. Morris, J. Phys. Chem. 100, 19227 (1996); H. Wang and W. L. Hase, Chem. Phys. 212, 247 (1996).
    • (1996) Chem. Phys. , vol.212 , pp. 247
    • Wang, H.1    Hase, W.L.2
  • 34
    • 1842283381 scopus 로고    scopus 로고
    • note
    • Earlier investigation of the translational energy dependence of Eq. 1 (6) did not cover a large enough energy range to be conclusive.
  • 36
    • 0012459682 scopus 로고
    • Standard Reference Database 19B, National Institute of Standards and Technology, Gaithersburg, MD
    • J. E. Bartmess, NIST Negative Ion Energetics Database, Version 3.0 (Standard Reference Database 19B, National Institute of Standards and Technology, Gaithersburg, MD, 1993).
    • (1993) NIST Negative Ion Energetics Database, Version 3.0
    • Bartmess, J.E.1
  • 37
    • 1842399954 scopus 로고    scopus 로고
    • note
    • Supported by NSF. S.L.C. was supported by an NSF predoctoral fellowship, an American Chemical Society Division of Organic Chemistry DuPont Merck Pharmaceutical Fellowship, and a John Stauffer Memorial Fellowship.


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