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Volumn 118, Issue 3, 1996, Pages 636-641

Ambident reactivity of enolate anions in the gas phase. Experimental determination of carbon vs oxygen acylation with CF3COCl

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EID: 0000082016     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9502233     Document Type: Article
Times cited : (35)

References (36)
  • 22
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    • Thesis, Stanford University
    • Wilbur, J. L. Thesis, Stanford University, 1993.
    • (1993)
    • Wilbur, J.L.1
  • 28
    • 0141826760 scopus 로고    scopus 로고
    • Brauman, J. I.; Lieder, C. A.; White, M. J. 1973, 95, 927
    • Brauman, J. I.; Lieder, C. A.; White, M. J. 1973, 95, 927.
  • 31
    • 3643086235 scopus 로고    scopus 로고
    • note
    • The stability difference of the products from the two channels is correlated with the energy difference between the keto and enol forms of the parent carbonyl compounds (see later discussion). The keto form is more stable than the enol form by at least 5 kcal/mol in this series (see Table 1).


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