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Volumn 36, Issue 13-14, 1997, Pages 1510-1512

Synthesis, Structure, and Reactivity of [Cp2Ti(HBcat)(PMe3)]: A Monoborane σ Complex

Author keywords

Boron; Complexes titanium; Coordination modes

Indexed keywords


EID: 0030864417     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199715101     Document Type: Article
Times cited : (71)

References (28)
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    • C. Hall, R. N. Perutz, Chem. Rev. 1996, 96, 3125-3146; see also J. J. Schneider, Angew. Chem. 1996, 108, 1132-1139; Angew. Chem. Int. Ed. Engl. 1996, 35, 1068-1076.
    • (1996) Angew. Chem. , vol.108 , pp. 1132-1139
    • Schneider, J.J.1
  • 10
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    • C. Hall, R. N. Perutz, Chem. Rev. 1996, 96, 3125-3146; see also J. J. Schneider, Angew. Chem. 1996, 108, 1132-1139; Angew. Chem. Int. Ed. Engl. 1996, 35, 1068-1076.
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    • note
    • 2 converged at R1 = 0.0638, wR2 = 0.1631, and GOF = 1.024. The hydrogen atoms were located and refined isotropically. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100125. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road. Cambridge CB21EZ, UK (fax: int. code +(1223)336-033; e-mail: deposit@chemcrys.cam.ac.uk).
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    • J. F. Hartwig, X. He, Angew Chem, 1996, 108, 352-354; Angew. Chem. Int. Ed. Engl. 1996, 35, 315-317.
    • (1996) Angew Chem , vol.108 , pp. 352-354
    • Hartwig, J.F.1    He, X.2
  • 18
    • 33748616497 scopus 로고    scopus 로고
    • J. F. Hartwig, X. He, Angew Chem, 1996, 108, 352-354; Angew. Chem. Int. Ed. Engl. 1996, 35, 315-317.
    • (1996) Angew. Chem. Int. Ed. Engl. , vol.35 , pp. 315-317
  • 19
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    • note
    • 2] (2.439-2.483 Å). Despite the smaller size of Ti, the Ti-B bond length in 2 (2.267 Å) is comparable to that of tungstenocene-(2.23 Å), tantalocene- (2.263 Å), and niobocene-boryl complexes (2.295 Å), which demonstrates partial Ti-B bonding in 2 (see also Figure 1).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.