Large-cage zeolite structures with multidimensional 12-ring channels

Science

Volumn 278, Issue 5346, 1997, Pages 2080-2085

  Bu, Xianhui ^a   Feng, Pingyun ^a   Stucky, Galen D ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b University of California   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ZEOLITE;

ARTICLE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; MOLECULAR INTERACTION; PRIORITY JOURNAL; SYNTHESIS;

EID: 0031457318     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.278.5346.2080     Document Type: Article

References (27)

1. W. M. Meier, D. H. Olson, Ch. Baerlocher, Atlas of Zeolite Structure Types (Elsevier, Boston, MA, 1996); H. van Bekkum, E. M. Flanigen, J. C. Jansen, Eds., Introduction to Zeolite Science and Practice (Elsevier, Amsterdam, 1991); D. W. Breck, Zeolite Molecular Sieves (Wiley, New York, 1974).
2. W. M. Meier, D. H. Olson, Ch. Baerlocher, Atlas of Zeolite Structure Types (Elsevier, Boston, MA, 1996); H. van Bekkum, E. M. Flanigen, J. C. Jansen, Eds., Introduction to Zeolite Science and Practice (Elsevier, Amsterdam, 1991); D. W. Breck, Zeolite Molecular Sieves (Wiley, New York, 1974).
3. W. M. Meier, D. H. Olson, Ch. Baerlocher, Atlas of Zeolite Structure Types (Elsevier, Boston, MA, 1996); H. van Bekkum, E. M. Flanigen, J. C. Jansen, Eds., Introduction to Zeolite Science and Practice (Elsevier, Amsterdam, 1991); D. W. Breck, Zeolite Molecular Sieves (Wiley, New York, 1974).
4. M. E. Davis, C. Saldarriaga, C. Montes, J. Garces, C. Crowder, Nature 331, 698 (1988); R. M. Dessan, J. L. Schlenker, J. B. Higgins, Zeolites 10, 552 (1990); C. C. Freyhardt, M. Tsapatsis, R. F. Lobo, K. J. Balkus Jr., M. E. Davis, Nature 381, 295 (1996).
5. M. E. Davis, C. Saldarriaga, C. Montes, J. Garces, C. Crowder, Nature 331, 698 (1988); R. M. Dessan, J. L. Schlenker, J. B. Higgins, Zeolites 10, 552 (1990); C. C. Freyhardt, M. Tsapatsis, R. F. Lobo, K. J. Balkus Jr., M. E. Davis, Nature 381, 295 (1996).
6. M. E. Davis, C. Saldarriaga, C. Montes, J. Garces, C. Crowder, Nature 331, 698 (1988); R. M. Dessan, J. L. Schlenker, J. B. Higgins, Zeolites 10, 552 (1990); C. C. Freyhardt, M. Tsapatsis, R. F. Lobo, K. J. Balkus Jr., M. E. Davis, Nature 381, 295 (1996).
7. R. H. Richard et al., J. Solid State Chem. 102, 204 (1993); M. Estermann, L. B. McCuster, C. Baerlocher, A. Merrouche, H. Kessler, Nature 352, 320 (1991).
8. R. H. Richard et al., J. Solid State Chem. 102, 204 (1993); M. Estermann, L. B. McCuster, C. Baerlocher, A. Merrouche, H. Kessler, Nature 352, 320 (1991).
9. M. I. Khan et al., Chem. Mater. 8, 43 (1996).
10. T. R. Gaffney, Curr. Opin. Solid State Mater. Sci. 1, 69 (1996).
11. L. B. McCuster, in Comprehensive Supramolecular Chemistry, G. Alberti and T. Bein, Eds. (Elsevier, New York, 1996), vol. 7, pp. 393-423.
12. P. Feng, X. Bu, G. D. Stucky, Nature 388, 735 (1997).
13. M. E. Davis and S. I. Zones, in Synthesis of Porous Materials, Zeolites, Clays, and Nanostructures, M. L. Occelli and H. Kessler, Eds. (Dekker, New York, 1996), pp. 1-34.
14. J. M. Bennett and B. K. Marcus, in Innovation in Zeolite Materials Science, P. J. Grober, W. J. Mortier, E. F. Vansant, G. Schulz-Ekloff, Eds. (Elsevier, New York, 1980), pp. 269-279; P. A. Wright et al., J. Chem. Soc. Chem. Commun. 1993, 633 (1993).
15. J. M. Bennett and B. K. Marcus, in Innovation in Zeolite Materials Science, P. J. Grober, W. J. Mortier, E. F. Vansant, G. Schulz-Ekloff, Eds. (Elsevier, New York, 1980), pp. 269-279; P. A. Wright et al., J. Chem. Soc. Chem. Commun. 1993, 633 (1993).
16. P. Feng, X. Bu, G. D. Stucky, Angew. Chem. Int. Ed. Engl. 34, 1745 (1995).
17. Q. Huo et al. Science 268, 1324 (1995).
18. 2 (7 ≤ n ≤ 12), have been used tor some time in the synthesis of microporous materials and are known to be the structure-directing agents in the crystallization of multidimensional high-silica zeolites ZSM-5 and ZSM-11 (E. W. Valyocsik and L. D. Rollmann, Zeolites 5, 123 (1985)].
19. S. T. Wilson and E. M. Flanigen, in Zeolite Synthesis, M. L. Occelli and H. E. Robson, Eds. (ACS Symposium Series 398, American Chemical Society, Washington, DC, 1989), pp. 329-345.
20. 4-11 was reported; however, the concentration of Mn is too low to have an effect on the structural refinement [J. J. Pluth et al., J. Phys. Chem. 92, 2734 (1988)].
21. H. Kessler, J. Patarin, C. Schott-Darie, in Studies in Surface Science and Catalysis, J. C. Jansen, M. Stocker, H. G. Karge, J. Weitkamp, Eds. (Elsevier, New York, 1994), vol. 85, pp. 75-113.
22. A. M. Chippindale and A. R. Cowley, Zeolites 18, 176 (1997).
23. X. Bu, T. E. Gier, P. Feng, G. D. Stucky, Microporous Mater., in press.
24. R. D. Shannon, Acta Crystallogr. A 32, 751 (1976).
25. L. B. McCuster, G. O. Brunner, A. F. Oju, ibid. 46, C55 (1990); K. J. Andries and J. V. Smith, in preparation.
26. L. B. McCuster, G. O. Brunner, A. F. Oju, ibid. 46, C55 (1990); K. J. Andries and J. V. Smith, in preparation.
27. Synthesis procedures and analytical data are available at http://www.sciencemag.org/feature/data/974117. shl. We thank Q. Huo for helpful discussions and D. Pierce from the Department of Geological Sciences for help with the electron probe microanalysis. This work was supported in part by the National Science Foundation under grant DMR 95-20971 and the U.S. Army Research Office under grant DAAH04-96-1-0443. A Materials Research Laboratory Corning Foundation Fellowship for P.F. is gratefully acknowledged.