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M. Berggren, O. Inganas, G. Gustafsson, J. Rasmusson, M. R. Andersson, T. Hjertberg, O. Wennerstrom, O. Nature 1994, 372, 444-446. M. Aguiar, F. E. Karasz, L. Akcelrud, Macromolecules 1995, 28, 4598-4602. S.-J. Chung, J.-I. Jin, K.-K. Kim, Adv. Mater. 1997, 9, 551-554. T. Christ, A. Greiner, R. Sander, V. Stümpften, J, H. Wendorff, Adv. Mater. 1997, 9, 219-222. S. E. Döttinger, M. Hohloch, J. L. Segura, E. Steinhuber, M. Hanack, A. Tompert, D. Oelkrug, Adv. Mater. 1997, 9, 233-236. E. M. Girotto, M.-A. De Paoli, Adv. Mater. 1998, 10, 790-793. L. Dähne, E. Biller, H. Baumgärtel, Angew. Chem. 1998, 110, 669-672; Angew. Chem. Int. Ed. 1998, 37, 646-649.
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15
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0002150218
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For recent articles discussing the modulation of the electronic properties of 2,2′:6′,2″-terpyridine-containing chromophores and complexes, see: a) F. Barigelletti, L. Flamigni, G. Calogero, L. Hammarstrom, J.-P. Sauvage, J.-P. Collin, Chem. Commun. 1998, 2333-2334;
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Collin, J.-P.6
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16
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0001719207
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b) M. Hissler, A. El-Ghayoury, A. Harriman, R. Ziessel, Angew. Chem. 1998, 110, 1804-1807; Angew. Chem. Int. Ed. 1998, 37, 1717-1720;
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Hissler, M.1
El-Ghayoury, A.2
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17
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-
25
-
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0344809576
-
-
note
-
Derivative 3d is somewhat susceptible to oxidation. Its fluorescence quantum yield was not determined since its emission wavelength is significantly red-shifted compared to the standard's emission.
-
-
-
-
26
-
-
0344377812
-
-
note
-
3) also shows tunability of emission wavelengths. This ligand is, however, a poorer binder due to the reduced electron density on the chelating nitrogens. Monosubstituted derivatives (e. g., 3-(tolylethynyl)-1,10-phenanthroline) typically show shorter absorption and emission wavelengths as well as lower fluorescence quantum efficiency, when compared to their disubstituted derivatives. This may enable fine-tuning of the absorption and emission characteristics. See Supporting Information for spectral data.
-
-
-
-
27
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0011410469
-
-
Ed.: D. L. Andrews, Springer, Berlin
-
C. S. Creaser, J. R. Sodeau, in Perspectives in Modern Chemical Spectroscopy, (Ed.: D. L. Andrews), Springer, Berlin, 1990, pp. 103-136.
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-
Creaser, C.S.1
Sodeau, J.R.2
-
28
-
-
0344809575
-
-
note
-
The emission spectra of the various ligands are insensitive to dioxygen. This further supports the assignment of a singlet π-π* as the emissive state.
-
-
-
-
29
-
-
85087575709
-
-
note
-
2+.
-
-
-
-
30
-
-
85087574803
-
-
note
-
+ (415 nm).
-
-
-
-
31
-
-
0031191655
-
-
and references therein
-
A. P. de Silva, H. Q. N. Gunaratne, T. Gunnlaugsson, A. J. M. Huxley, C. P. McCoy, J. T. Rademacher, T. E. Rice, Chem. Rev. 1997, 97, 1515-1566, and references therein.
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De Silva, A.P.1
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McCoy, C.P.5
Rademacher, J.T.6
Rice, T.E.7
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36
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37049083525
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For 2,9-bisaryl-1,10-phenanthrolines and their luminescence properties, see: N. Armaroli, L. De Cola, V. Balzani, J.-P. Sauvage, C. O. Dietrich-Buchecker, J.-M. Kern, J. Chem. Soc. Faraday Trans. 1992, 88, 553-556.
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37
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37049077491
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For an intriguing tunable 2-catenand, see: N. Armaroli, L. De Cola, V. Balzani, J.-P. Sauvage, C. O. Dietrich-Buchecker, J.-M. Kern, A. Bailal, J. Chem. Soc. Dalton Trans. 1993, 3241-3247. For metal-binding conjugated polymers, see: S. S. Zhu, P. J. Carroll, T. M. Swager, J. Am. Chem. Soc. 1996, 118, 8713-8714; B. Wang, M. R. Wasielewski, J. Am. Chem. Soc. 1997, 119, 12-21; K. B. Crawford, M. B. Goldfinger, T. M. Swager, J. Am. Chem. Soc. 1998, 120, 5187-5192; M. Kimura, T. Horai, K. Hanabusa, H. Shirai, Adv. Mater. 1998, 10, 459-462.
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Kern, J.-M.6
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38
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0029819478
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For an intriguing tunable 2-catenand, see: N. Armaroli, L. De Cola, V. Balzani, J.-P. Sauvage, C. O. Dietrich-Buchecker, J.-M. Kern, A. Bailal, J. Chem. Soc. Dalton Trans. 1993, 3241-3247. For metal-binding conjugated polymers, see: S. S. Zhu, P. J. Carroll, T. M. Swager, J. Am. Chem. Soc. 1996, 118, 8713-8714; B. Wang, M. R. Wasielewski, J. Am. Chem. Soc. 1997, 119, 12-21; K. B. Crawford, M. B. Goldfinger, T. M. Swager, J. Am. Chem. Soc. 1998, 120, 5187-5192; M. Kimura, T. Horai, K. Hanabusa, H. Shirai, Adv. Mater. 1998, 10, 459-462.
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39
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0031055520
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-
For an intriguing tunable 2-catenand, see: N. Armaroli, L. De Cola, V. Balzani, J.-P. Sauvage, C. O. Dietrich-Buchecker, J.-M. Kern, A. Bailal, J. Chem. Soc. Dalton Trans. 1993, 3241-3247. For metal-binding conjugated polymers, see: S. S. Zhu, P. J. Carroll, T. M. Swager, J. Am. Chem. Soc. 1996, 118, 8713-8714; B. Wang, M. R. Wasielewski, J. Am. Chem. Soc. 1997, 119, 12-21; K. B. Crawford, M. B. Goldfinger, T. M. Swager, J. Am. Chem. Soc. 1998, 120, 5187-5192; M. Kimura, T. Horai, K. Hanabusa, H. Shirai, Adv. Mater. 1998, 10, 459-462.
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Wang, B.1
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40
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0032478979
-
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For an intriguing tunable 2-catenand, see: N. Armaroli, L. De Cola, V. Balzani, J.-P. Sauvage, C. O. Dietrich-Buchecker, J.-M. Kern, A. Bailal, J. Chem. Soc. Dalton Trans. 1993, 3241-3247. For metal-binding conjugated polymers, see: S. S. Zhu, P.J. Carroll, T. M. Swager, J. Am. Chem. Soc. 1996, 118, 8713-8714; B. Wang, M. R. Wasielewski, J. Am. Chem. Soc. 1997, 119, 12-21; K. B. Crawford, M. B. Goldfinger, T. M. Swager, J. Am. Chem. Soc. 1998, 120, 5187-5192; M. Kimura, T. Horai, K. Hanabusa, H. Shirai, Adv. Mater. 1998, 10, 459-462.
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Crawford, K.B.1
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41
-
-
0032046547
-
-
For an intriguing tunable 2-catenand, see: N. Armaroli, L. De Cola, V. Balzani, J.-P. Sauvage, C. O. Dietrich-Buchecker, J.-M. Kern, A. Bailal, J. Chem. Soc. Dalton Trans. 1993, 3241-3247. For metal-binding conjugated polymers, see: S. S. Zhu, P.J. Carroll, T. M. Swager, J. Am. Chem. Soc. 1996, 118, 8713-8714; B. Wang, M. R. Wasielewski, J. Am. Chem. Soc. 1997, 119, 12-21; K. B. Crawford, M. B. Goldfinger, T. M. Swager, J. Am. Chem. Soc. 1998, 120, 5187-5192; M. Kimura, T. Horai, K. Hanabusa, H. Shirai, Adv. Mater. 1998, 10, 459-462.
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Kimura, M.1
Horai, T.2
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Shirai, H.4
-
45
-
-
85087575878
-
-
note
-
F = 0.94 is predicted for 3b. See Supporting Information for detailed calculations.
-
-
-
|