Metal-directed assembly of triple-layered fluorescent metallocyclophanes [6]

Journal of the American Chemical Society

Volumn 121, Issue 26, 1999, Pages 6316-6317

  Holliday, Bradley J ^a   Farrell, Joshua R ^a   Mirkin, Chad A ^a   Lam, Kin Chung ^b   Rheingold, Arnold L ^b  

^a NORTHWESTERN UNIVERSITY   (United States)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FLUORESCENT DYE;

CHEMICAL ANALYSIS; ELECTRON TRANSPORT; LETTER; MOLECULAR INTERACTION; PHOTOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0033532903     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991140f     Document Type: Letter

References (30)

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22. 2) = 6.86% for 8635 observed independent reflections (3.54° ≤ 2θ ≤ 48.00°). The asymmetric contains half of the rhodium cation, a tetrafluoroborate anion, three molecules of dichloromethane, and half a molecule of an acetonitrile residing along a 2-fold axis.
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27. max = 386 nm(ε = 60 700).
28. The large decrease in observed fluorescence intensity in 3b is due to "trivial quenching" (quenching due to the reabsorption of emitted light within the sample, not competing decay processes such as energy or electron transfer) as the CT absorption (466 nm) significantly overlaps with the fluorescence emission (442 nm) of the unperturbed anthracene chromophore.
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