Amine phosphates as intermediates in the formation of open-framework structures

Angewandte Chemie - International Edition

Volumn 38, Issue 23, 1999, Pages 3480-3483

  Neeraj, S ^a   Natarajan, Srinivasan ^a   Rao, C N R ^a  

^a JAWAHARLAL NEHRU CENTRE FOR ADVANCED SCIENTIFIC RESEARCH   (India)

Author keywords

Hydrothermal syntheses; Phosphorus; Tin; Zinc

Indexed keywords

AMINE; METAL ION; PHOSPHATE; PIPERAZINE DERIVATIVE; TIN; ZINC ION;

ARTICLE; CHEMICAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS; TEMPERATURE; X RAY DIFFRACTION;

EID: 0033521202     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19991203)38:23<3480::AID-ANIE3480>3.0.CO;2-S     Document Type: Article

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25. 31P NMR signal (δ-3.82) whose intensity first increases with time and then decreases due to the formation of a edge-shared ladder or layer structures. We consider the initial phosphate material formed to be the precursor, since on further reaction or passage of time it gives the more complex ladder, layer, or three-dimensional structures. It seems likely that the precursor is a corner-shared linear ladder phosphate which we have isolated from some reactions of the amine phosphates. Accordingly, the Zn:P ratio in the precursor phosphate is 1:1 (in contrast to the edge-shared ladder phosphates, in which it is 1:2).
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