Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments?

Angewandte Chemie - International Edition

Volumn 38, Issue 17, 1999, Pages 2565-2568

  Weinberger, Dana A ^a   Higgins, Thomas B ^a   Mirkin, Chad A ^a   Liable Sands, Louise M ^b   Rheingold, Arnold L ^b  

^a NORTHWESTERN UNIVERSITY   (United States)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

Conducting materials; P ligands; Polymers; Redox chemistry; Ruthenium

Indexed keywords

COORDINATION COMPOUND; LIGAND; METAL COMPLEX; POLYMER; RUTHENIUM; TIENILIC ACID;

ARTICLE; CHEMICAL BINDING; CHEMICAL REACTION; COMPLEX FORMATION; ELECTROCHEMICAL ANALYSIS; LIGAND BINDING; OXIDATION REDUCTION POTENTIAL; OXIDATION REDUCTION REACTION; POLYMERIZATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 0033520392     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990903)38:17<2565::AID-ANIE2565>3.0.CO;2-U     Document Type: Article

References (23)

1. a) J. W. Benson, R. J. Angelici, Organometallics 1992, 11, 922;
2. b) J. W. Benson, R. J. Angelici, Organometallics 1993, 12, 680.
3. a) M. O. Wolf, M. S. Wrighton, Chem. Mater. 1994, 6, 1526;
4. b) A. Shaver, I. A. Butler, J. P. Gao, Organometallics 1989, 8, 2079;
5. c) T. B. Higgins, C. A. Mirkin, Chem. Mater. 1998, 10, 1589;
6. d) T. B. Higgins, C. A. Mirkin, Inorg. Chim. Acta 1995, 240, 347;
7. e) J. L. Reddinger, J. R. Reynolds, Chem. Mater. 1998, 10, 1236;
8. f) K. F. Martin, T. W. Hanks, Organometallics 1997,16, 4857;
9. g) K. Martin, M. Dotson, M. Litterer, T. W. Hanks, C. Veas, Synth. Met. 1996, 78, 161;
10. h) S. S. Zhu, P. J Carroll, T. M. Swager, J. Am. Chem. Soc. 1996, 118, 8713.
11. a) A. M. Allgeier, C. S. Slone, C. A. Mirkin, L. M. Liable-Sands, G. P. A. Yap, A. L. Rheingold, J. Am. Chem. Soc. 1997, 119, 550;
12. b) C. S. Stone, C. A. Mirkin, G. P. A. Yap, I. A. Guzei, A. L. Rheingold, J. Am. Chem. Soc. 1997, 119, 10743;
13. c) C. A. Sassano, C. A. Mirkin, J. Am. Chem. Soc. 1995, 117, 11379;
14. d) E. T. Singewald, C. A. Mirkin, C. L. Stern, Angew. Chem. 1995, 107, 1725; Angew. Chem. Int. Ed. Engl. 1995, 34, 1624;
15. d) E. T. Singewald, C. A. Mirkin, C. L. Stern, Angew. Chem. 1995, 107, 1725; Angew. Chem. Int. Ed. Engl. 1995, 34, 1624;
16. e) A. M. Allgeier, E. T. Singewald, C. A. Mirkin, C. L. Stern, Organometallics 1994, 13, 2928.
17. A. P. Humphries, S. A. R. Knox, J. Chem. Soc. Dalton Trans. 1975, 1710.
18. -3, R(F) = 0.0514 for 9428 observed independent reflections (4° ≤ 2θ ≤ 57°). Further details on the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen, Germany (fax: (+49)7247-808-666); e-mail: crysdata@fiz-karlsruhe.de), on quoting the depository number CSD-410356.
19. 3, lone pair), see K. Stanley, M. C. Baird, J. Am. Chem. Soc. 1975, 97, 6598.
20. a) D. D. Graf, K. R. Mann, Inorg. Chem. 1997, 36, 150;
21. b) D. D. Graf, N. C. Day, K. R. Mann, Inorg. Chem. 1995, 34, 1562. For reviews of thiophene coordination: c) T. B. Rauchfuss, Prog. Inorg. Chem. 1991, 39, 259-329;
22. b) D. D. Graf, N. C. Day, K. R. Mann, Inorg. Chem. 1995, 34, 1562. For reviews of thiophene coordination: c) T. B. Rauchfuss, Prog. Inorg. Chem. 1991, 39, 259-329;
23. d) R. J. Angelici, Coord. Chem. Rev. 1990, 105, 61.