Soluble organoiron derivatives of polypyrrole

Organometallics

Volumn 16, Issue 22, 1997, Pages 4857-4860

  Martin, K F ^a   Hanks, T W ^a  

^a FURMAN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0003180537     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970257e     Document Type: Article

References (35)

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23. 1/2)], 401.6 [N(1s), 20%], 399.8 [N(1s), 80%].
24. Thermal gravimetric analyses were performed on a Perkin-Elmer TGA 7 analyzer. All samples had a mass of approximately 10 mg. All calculations were performed on data represented as percent loss of starting mass. Fp-pyr and polymer films were heated at a constant rate of 5 °C/min from 25 to 1000 °C. Mass loss and onset calculations were performed by standard methods.
25. 5 in inert polymer matrices, See: Mejdrich, A.; Hanks, T. W. Synth. React. Inorg. Met.-Org. Chem., submitted for publication.
26. 1/2)], 401.7 [N(1s), 52%], 399.8 [N(1s), 48%].
27. An examination of the metal-ligand stretching region in the far-IR did not provide unambiguous evidence of a ring-slip process.
28. Attempts were made to convert 3 back into 2 by bubbling CO through methylene chloride solutions of the polymer for 4 h. No change was observed by IR spectroscopy. Exposing the solution of compound 3 to 3 atm of CO for 48 h with agitation also had no effect.
29. 13d Due to the good conductivity of the samples, charging was not a major problem in any case. Errors are conservatively estimated at ±0.3 eV.
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35. 4 as the supporting electrolyte.