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7-water system is determined by DSC and optical microscopy. Interesting three-phase equilibria have been revealed. However, the conclusion that the solid surfactant-water compound is formed is wrong; the DSC data clearly indicate existence of a eutectic phase transition in which a liquid crystal phase is formed out of solid surfactant phase and ice
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7-water system is determined by DSC and optical microscopy. Interesting three-phase equilibria have been revealed. However, the conclusion that the solid surfactant-water compound is formed is wrong; the DSC data clearly indicate existence of a eutectic phase transition in which a liquid crystal phase is formed out of solid surfactant phase and ice.
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4-water system is presented. Same comments as for the preceding article.
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2H-NMR and SAXS. Lamellar and defective lamellar phases have been found. A metastable rhombohedral mesh intermediate phase is identified on cooling. The thermodynamically stable phase in this region is the cubic Ia3d phase.
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2H-NMR and SAXS. Lamellar and defective lamellar phases have been found. A metastable rhombohedral mesh intermediate phase is identified on cooling. The thermodynamically stable phase in this region is the cubic Ia3d phase.
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+) and of unbound nanodisks have been depicted in the water-rich corner of the isothermal ternary phase diagram
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+ ) and of unbound nanodisks have been depicted in the water-rich corner of the isothermal ternary phase diagram.
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Lyotropic mesophases of a fluorinated surfactant with a short nonionic polar head in water
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α phase, in my view, should be depicted as an azeotrope point.
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2O system. The regions of isotropic micellar solution, nematic phase with disklike micelles, lamellar phase, crystals and biphasic regions have been depicted
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2O system. The regions of isotropic micellar solution, nematic phase with disklike micelles, lamellar phase, crystals and biphasic regions have been depicted.
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Phase behavior and phase structure of a cationic fluorosurfactant in water
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1, two intermediate (centered rectangular and centered trigonal), lamellar and random mesh phase has been found
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1, two intermediate (centered rectangular and centered trigonal), lamellar and random mesh phase has been found.
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14NO and Ca dodecyl sulfate yielded phase states with interesting rheological behavior. The phase state consisting of densely packed vesicles is described. Surface tension measurements show a strong synergism
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14NO and Ca dodecyl sulfate yielded phase states with interesting rheological behavior. The phase state consisting of densely packed vesicles is described. Surface tension measurements show a strong synergism.
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Novel gel phase: A cubic phase of densely packed monodisperse, unilamellar vesicles
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•In the Na oleate/octanol/water system a new phase state is observed in which the mixture is transparent, isotropic, highly viscous and possesses elastic properties. It is concluded that it consists of a highly ordered, dense array of monodisperse, unilamellar vesicles
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Swelling and dissolution of lamellar phases: role of bilayer organization
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•The swelling and dissolution of the lamellar phase is studied by optical microscopy in penetration-scan experiments on an AOT/NaCl/water system. By shearing the lamellar phase prior to contact, a metastable state of close-packed lamellar vesicles is prepared. The term 'onion phase' for this state is unfortunate, in my opinion, as this is a biphasic state, not a single phase
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Buchanan M, Arrault J, Cates ME. Swelling and dissolution of lamellar phases: role of bilayer organization. Langmuir 1998;14:7371-7377. •The swelling and dissolution of the lamellar phase is studied by optical microscopy in penetration-scan experiments on an AOT/NaCl/water system. By shearing the lamellar phase prior to contact, a metastable state of close-packed lamellar vesicles is prepared. The term 'onion phase' for this state is unfortunate, in my opinion, as this is a biphasic state, not a single phase.
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3 phase. A detailed phase diagram is presented.
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Liquid crystal templates for nanostructured metals
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8-water system has been used as a medium for nanostructure design. Reduction of platinum salts in its aqueous domains yielded metallic platinum whose nanostructure is a direct cast of the liquid crystal phase architecture. Platinum particles have regular cylindrical pores in a continuous metallic matrix
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8-water system has been used as a medium for nanostructure design. Reduction of platinum salts in its aqueous domains yielded metallic platinum whose nanostructure is a direct cast of the liquid crystal phase architecture. Platinum particles have regular cylindrical pores in a continuous metallic matrix.
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Clunie J.S., Goodman J.F., Symons P.C. Phase equilibria of dodecylhexaoxyethylene glycol monoether in water. Trans Faraday Soc. 65:1969;287-296.
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••A third part of the series of papers describing the equilibrium phase diagram, kinetics of phase reactions and colloidal aspects of the behavior of DODMAC-water system. Heating dilute aqueous mixtures of the DODMAC monohydrate yields a gel-like state which is an irreversible colloidal structure. The collapse of the colloidal structure produces single crystals
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Laughlin RG, Munyon RL, Burns JL, Coffindaffer TW, Talmon Y. Physical science of the dioctadecyldimethylammonium chloride-water system. 3. Colloidal aspects. J Phys Chem 1992;96:374-383. ••A third part of the series of papers describing the equilibrium phase diagram, kinetics of phase reactions and colloidal aspects of the behavior of DODMAC-water system. Heating dilute aqueous mixtures of the DODMAC monohydrate yields a gel-like state which is an irreversible colloidal structure. The collapse of the colloidal structure produces single crystals.
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