Remarkable regioselectivity in the reaction between [(η5-C5Me4H)RhCl(μ-Cl)]2 and (C6F5)2PCH2CH2P(C6F5)2: Synthesis of a chiral-at-metal rhodium complex cation via carbon-fluorine and -hydrogen bond activation and carbon-carbon bond formation

Journal of Organometallic Chemistry

Volumn 558, Issue 1-2, 1998, Pages 209-212

  Atherton, Malcolm J ^a   Holloway, John H ^b   Hope, Eric G ^b   Saunders, Graham C ^b,c  

^a F2 Chemicals Ltd   (United Kingdom)

^b UNIVERSITY OF LEICESTER   (United Kingdom)

^c QUEEN'S UNIVERSITY BELFAST   (United Kingdom)

Author keywords

Bond activation; Chiral at metal rhodium complex; Regioselectivity

Indexed keywords

EID: 0000807413     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)00428-8     Document Type: Article

References (18)

1. (a) J.L. Kiplinger, T.G. Richmond, C.E. Osterberg, Chem. Rev. 94 (1994), 373.
2. (b) G.C. Saunders, Angew. Chem. Int. Ed. Engl. 35 (1996) 2615.
3. (c) J. Burdeniuc, B. Jedlicka, R.H. Crabtree, Chem. Ber. 130 (1997) 145.
4. (a) M. Aizenberg, D. Milstein, J. Am. Chem. Soc. 117 (1995) 8674.
5. (b) J.L. Kiplinger, T.G. Richmond, Chem. Commun. (1996) 1115.
6. Kiplinger J.L., Richmond T.G. J. Am. Chem. Soc. 118:1996;1805.
7. Burdeniuc J., Crabtree R.H. J. Am. Chem. Soc. 118:1996;2525.
8. (a) R.E.J. Bichler, M.R. Booth, H.C. Clark, J. Organomet. Chem. 24 (1970) 145.
9. (b) M.I. Bruce, B.L. Goodall, G.L. Sheppard, F.G.A. Stone, J. Chem. Soc. Dalton Trans. (1975) 591.
10. (c) T.G. Dietz, D.S. Chatellier, D.P. Ridge, J. Am. Chem. Soc. 100 (1978) 4905.
11. (d) A. Bjarnason, J.W. Taylor, Organometallics 8 (1989) 2020.
12. (e) J.A.K. Howard, S.A.R. Knox, N.J. Terrill, M.I. Yates, Chem. Commun. (1989) 640.
13. (f) J. Powell, M. Horvath, Organometallics 12 (1993) 4073.
14. M.J. Atherton, J. Fawcett, J.H. Holloway, E.G. Hope, A. Karaçar, D.R. Russell, G.C. Saunders, Chem. Commun. (1995) 191.
15. M.J. Atherton, J. Fawcett, J.H. Holloway, E.G. Hope, A. Karaçar, D.R. Russell, G.C. Saunders, J. Chem. Soc. Dalton Trans. (1996) 3215.
16. M.J. Atherton, J.H. Holloway, E.G. Hope, S.M. Martin, G.C. Saunders, J. Organomet. Chem. 555 (1998) 67.
17. (a) S.L. Hart, D.J. Duncalf, J.J. Hastings, A. McCamley, P.C. Taylor, J. Chem. Soc. Dalton Trans. (1996) 2843.
18. (b) D. Carmona, F.J. Lahoz, L.A. Oro, M.P. Lamata, F. Viguri, E. San José, Organometallics 15 (1996) 2961, and references cited therein.