On the reduction steps in the mevalonate independent 2-C-methyl-D-erythritol 4-phosphate (MEP) pathway for isoprenoid biosynthesis in the bacterium Zymomonas mobilis

Tetrahedron Letters

Volumn 40, Issue 40, 1999, Pages 7231-7234

  Charon, Lionel ^a   Pale Grosdemange, Catherine ^a   Rohmer, Michel ^a  

^a UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

DEUTERIUM; GLUCOSE; ISOMERASE; ISOPRENOID; MEVALONIC ACID; ORGANOPHOSPHORUS COMPOUND; REDUCED NICOTINAMIDE ADENINE DINUCLEOTIDE PHOSPHATE; SUGAR PHOSPHATE; TRITERPENOID; XYLULOSE;

ARTICLE; BIOSYNTHESIS; CARBOHYDRATE METABOLISM; CHEMICAL ANALYSIS; GRAM NEGATIVE FACULTATIVELY ANAEROBIC RODS; ISOTOPE LABELING; NONHUMAN; REDUCTION; ZYMOMONAS MOBILIS;

EID: 0033214921     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01531-2     Document Type: Article

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24. 2c
25. 1H decoupling by WALTZ 16 during acquisition and relaxation.
26. 2H induced shift (ppb) = C-1 (40.346/α-shift: -393, t, 20Hz), C-2 and C-6, (18.697/β-shifts: -105 and -198, biogenetically equivalent, both corresponding to C-1 of IPP), C-3 (42.086, broad signal/γ-shifts: -14 and -32). C-4 (33.257/β-shifts: -77 and -160), C-5 (56.084, broad signal due to up to 5 γ-shifts, no delectable α-shift), C-7 (33.305/α-shift: -364, t, J=20 Hz), C-8* (41.818/β-shifts: -89 and -165), C-9 (50.461/β-shift: -38), C-10 (37.408/β-shifts: -93 and -179). C-11 (20.974, possible shifted signal concealed by those of the acetoxy methyl groups), C-12 (23.985), C-13 (49.337/β-shift: -45), C-14* (41.700/β-shifts: -87 and -163), C-15 (33.708/possible α-shifted signal concealed by the signals of C-7, C-4 and C-23), C-16 (22.784/β-shifts: -83 and -188), C-17 (54.408, broadening of the peak, no measurable β-shift), C-18 (44.382/β-shifts: -80 and -169), C-19 (41.569/α-shift: -390, t, J=20 Hz), C-20 (27.603/β-shifts: -93 and -198), C-21 (45.946/no delectable α- or β-shifts, γ-shift: -16), C-22 (36.150/β-shifts: -70 and 141) C-23 (33.411/α-shift: -313,t, J=20 Hz), C-24 (21.593/γ-shifts: -26 and -45), C-25 (15.910/γ-shifts: -35 and -48), C-26° (16.615/γ-shifts:-13 and -29), C-27° (16.536/γ-shifts: -16 and -29), C-28 (15.875/γ-shifts: -29 and -42), C-29 (19.860/α-shift: -300, t, J=19 Hz), C-30 (30.767/γ-shift: -16). Assignments of signals bearing the same superscript may be interchanged.
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