Kinetics and Mechanism of the Dihydroxylation and Epoxidation of Conjugated Dienes with Hydrogen Peroxide Catalyzed by Methylrhenium Trioxide

Inorganic Chemistry

Volumn 37, Issue 3, 1998, Pages 467-472

  Tan, Haisong ^a   Espenson, James H ^a  

^a IOWA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000055274     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971073v     Document Type: Article

References (19)

1. Simándi, L. I. Catalytic Activation of Dioxygen by Metal Complexes; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; p 109.
2. Sheldon, R. A.; Kochi, J. K. Metal-Catalyzed Oxidations of Organic Compounds; Academic Press: New York, 1981; p 275.
3. Goor, G. In Catalytic Oxidations with Hydrogen Peroxide as Oxidant; Strukul, G., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; p 25.
4. Sheldon, R. A. Top. Chem. 1993, 164, 23.
5. Clerici, M. G.; Ingallina, P. Clean Oxidation Technologies: New Prospects in the Epoxidation of Olefms. In Green Chemistry; American Chemical Society: Washington, DC, 1996; Chapter 5.
6. Sheldon, R. A. Synthesis of Oxiranes. In Applied Homogeneous Catalysis with Organometallic Compounds; Cornelis, B., Herrmann, W. A., Eds.; VCH: Weinheim, Germany, 1996; Vol. 1, p 411.
7. Herrmann, W. A.; Fischer, R. W.; Scherer, W.; Rauch, M. U. Angew. Chem., Int. Ed. Engl. 1993, 32, 1157.
8. Herrmann, W. A.; Fischer, R. W.; Rauch, M. U.; Scherer, W. J. Mol. Catal. 1994, 86, 243.
9. Al-Ajlouni, A.; Espenson, J. H. J. Am. Chem. Soc. 1995, 117, 9243.
10. Al-Ajlouni, A.; Espenson, J. H. J. Org. Chem. 1996, 61, 3969.
11. Espenson, J. H. Chemical Kinetics and Reaction Mechanisms, 2nd ed.; McGraw-Hill, Inc.: New York, 1995.
12. Espenson, J. H.; Abu-Omar, M. M. Adv. Chem. Ser. 1997, No. 253, 99.
13. Hansen, P. J.; Espenson, J. H. Inorg. Chem. 1995, 34, 5839.
14. Wang, W.; Espenson, J. H. Inorg. Chem. 1997, in press.
15. Espenson, J. H. Chemical Kinetics and Reaction Mechanisms, 2nd ed.; McGraw-Hill, Inc.: New York, 1995.
16. Collman, J. P.; Brauraan, J. I.; Meunier, B.; Hayashi, T.; Kodadek, T.; Raybuck, S. A. J. Am. Chem. Soc. 1983, 107, 2000.
17. We are grateful to Professor R. J. Angelici for the idea of trying this correlation.
18. Long, F. A.; Pritchard, J. G. J. Am. Chem. Soc. 1956, 78, 2663.
19. Stewart, J. J. J. Comput. Chem. 1989, 10, 221.