One pot synthesis of 3,4-disubstituted 1-alkyl-4H-1,2,4-triazol-1-ium salts

Synthetic Communications

Volumn 29, Issue 1, 1999, Pages 1-9

  Teles, J H ^a   Breuer, K ^a   Enders, D ^b   Gielen, H ^b  

^a BASF SE   (Germany)

^b RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

1,3 DIMETHYL 4 ( 2 ACETOXY 2 PHENYL 1 METHYLETHYL) 4H 1,2,4 TRIAZOL 1 IUM PERCHLORATE; 1,3 DIMETHYL 4 (1 PHENYLETHYL) 4H 1,2,4 TRIAZOL 1 IUM PERCHLORATE; 1,3,4 TRIMETHYL 4H 1,2,4, TRIAZOL 1 IUM TETRAPHENYLBORATE; 1,4 DIMETHYL 3 PHENYL 4H 1,2,4 TRIAZOL 1 IUMCHLORIDE; 4,4' (1,6 HEXANDIYL) BIS(1 METHYL 3 PHENYL 4H 1,2,4 TRIAZOL 1 IUM DICHLORIDE); BENZOIN; CHLORIDE; HYDRAZINE DERIVATIVE; TRIAZOLE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL STRUCTURE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0033019620     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1080/00397919908085727     Document Type: Article

References (16)

1. (a) Enders, D., Breuer, K., Raabe, G., Runsink, J., Teles, J. H., Melder, J.-P., Ebel, K., Brode, S. Angew. Chem. 1995, 107, 1119; Angew. Chem., Int. Ed. Engl. 1995, 34, 1021;
2. (a) Enders, D., Breuer, K., Raabe, G., Runsink, J., Teles, J. H., Melder, J.-P., Ebel, K., Brode, S. Angew. Chem. 1995, 107, 1119; Angew. Chem., Int. Ed. Engl. 1995, 34, 1021;
3. (b) Enders, D., Breuer, K., Runsink, J., Teles, J. H. Liebigs Ann. 1996, 2019;
4. (c) Enders, D., Breuer, K., Teles, J. H., Ebel, K. J. Prakt. Chem. 1997, 339, 397.
5. (a) Teles, J. H., Melder, J.-P., Ebel, K., Schneider, R., Gehrer, E., Harder, W., Brode, S., Enders, D., Breuer, K., Raabe, G. Helv. Chim. Acta 1996, 79, 61;
6. (b) Enders, D., Breuer, K., Teles, J. H. Helv. Chim. Acta 1996, 79, 1217.
7. Enders, D., Breuer, K., Runsink, J., Teles, J. H. Helv. Chim. Acta 1996, 79, 1899.
8. (a) Enders, D., Gielen, H., Raabe, G., Runsink, J., Teles, J. H. Chem. Ber. 1996, 129, 1483;
9. (b) Enders, D., Gielen, H., Raabe, G., Runsink, J., Teles, J. H. Chem. Ber./Recueil 1997, 30, 1253;
10. (c) Enders, D., Gielen, H., Breuer, K. Tetrahedron: Asymm. 1997, 8, 3571;
11. (d) Enders, D., Gielen, H., Runsink, J., Breuer, K., Brode, S., Boehn, K. Eur. J. Inorg. Chem. 1998, in press.
12. Dorn, H., Zubek, A., Hilgetag, G. Chem. Ber. 1965, 98, 3377.
13. The structure contains two crystallographically independent molecules of both the anion and the cation and the methyl group at the 3 position of the triazolium cation shows rotational disorder. The crystallographical data (without structure factors) were deposited at the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-101601. Further details can be obtained from: The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ (Telefax: Int. +1223/336-033; E-mail: deposit@chemcrys.cam.ac.uk).
14. Duhamel, L., Plaquevent, J.-C. Bull. Soc. Chim. Fr. 1982, 2, 75.
15. Braun, J. v., Pinkernelle, W. Chem. Ber. 1934, 67, 1218.
16. Cirrincione, G., Hinz, W., Jones, R. A. J. Chem. Soc. Perkin Trans. 2 1984, 1089.