(S,S′)-4,4′-bis(3-hydroxy-estra-1,3,5(10),6,8-pentaene): An efficient ligand for the catalytic asymmetric oxidation of sulfides to sulfoxides

Synlett

Volumn , Issue 3, 1999, Pages 360-362

  Bolm, Carsten ^a   Dabard, Olivier A G ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Asymmetric catalysis; BINOL; Steroids; Sulfide oxidation; Titanium

Indexed keywords

LIGAND; STEROID; SULFIDE; SULFOXIDE; TITANIUM;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHIRALITY; ENANTIOMER; OXIDATION; REACTION ANALYSIS;

EID: 0032981404     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1999-2603     Document Type: Article

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42. 5 The enantiomeric ratio (91% ee) was determined by HPLC using a chiral column (Daicel Chiralcel OD). The (S)-configuration of the product was assigned by comparison with literature values.