Synthesis and photophysical properties of porphyrin-functionalized molecular clips

Journal of Organic Chemistry

Volumn 64, Issue 18, 1999, Pages 6653-6663

  Reek, Joost N H ^a,b   Rowan, Alan E ^a   Crossley, Maxwell J ^c   Nolte, Roeland J M ^a  

^a RADBOUD UNIVERSITY NIJMEGEN   (Netherlands)

^b UNIVERSITY OF AMSTERDAM   (Netherlands)

^c NONE

Author keywords

[No Author keywords available]

Indexed keywords

PORPHYRIN DERIVATIVE;

ARTICLE; CRYSTAL STRUCTURE; MOLECULAR INTERACTION; OXIDATION REDUCTION REACTION; PHOTOCHEMISTRY; REACTION ANALYSIS; SYNTHESIS;

EID: 0032885846     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo990348g     Document Type: Article

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48. 15
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52. SPC time-resolved fluorescence measurements performed on the complex of 2b with dihydroxybenzene showed no additional decay, suggesting that the electron transfer between the porphyrin and the quinone became faster than the detection limit. This indicates that the photoinduced electron transfer is faster when an aromatic guest is bound between the donor and the acceptor.