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85034564389
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note
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EDT-TTF oxidizes at 0.44 and 0.75, BEDT-TTF at 0.56 and 0.80 V vs. SCE under the same conditions.
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27
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0001470928
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4243628544
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Oxidized TTF moieties are well known to exhibit a lengthening of the central C=C bond with a concomitant shortening of the C-S bonds, while the two dithiole rings, often folded along the S-S axis in the neutral state, become fully planar in mixed-valence salts. See: a) A. Pénicaud, P. Batail, P. Davidson, A.-M. Levelut, C. Coulon, C. Perrin, Chem. Mater. 1990, 2, 117-123;
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0003502895
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Prentice-Hall, Inc., Englewood Cliffs, New Jersey
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The α-, β-, and κ-phase denominations refer to the geometrical patterns observed for the organic slabs in BEDT-TTF salts in which molecules of one stack form a marked dihedral angle with molecules on the adjacent stack (α); the molecules on adjacent stacks are parallel (β) ; the slab is paved with twisted donor dimers instead (κ): J. M. Williams, J. R. Ferraro, R. J. Thorn, K. D. Carlson, U. Geiser, H. H. Wang, A. M. Kini, M.-H. Whangbo in Organic Superconductors (Including Fullerenes): Synthesis, Structure, Properties and Theory, Prentice-Hall, Inc., Englewood Cliffs, New Jersey, 1992, p. 81.
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mn matrix elements were calculated according to the modified Wolfsberg-Helmholz formula [J. H. Ammeter, H.-B. Bürgi, J. Thibeault, R. Hoffmann, J. Am. Chem. Soc. 1978, 100, 3686-3692].
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mn matrix elements were calculated according to the modified Wolfsberg-Helmholz formula [J. H. Ammeter, H.-B. Bürgi, J. Thibeault, R. Hoffmann, J. Am. Chem. Soc. 1978, 100, 3686-3692].
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