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Volumn 2, Issue 10, 1996, Pages 1275-1282

Me3TTF-PO3H2, a redox phosphonic acid and its monoanilinium salt [PhNH3+][Me3TTF-PO(OH) O-], the electrocrystallized neutral (Zwitterionic) π radical [Me3TTF-PO(OH)O-]•+, and their associated lamellar constructions in the solid state

Author keywords

Crystal engineering; Hydrogen bonds; Phosphonates; Radical cations; Tetrathiafulvalenes

Indexed keywords

ELECTROCRYSTALLIZATION; INTERMOLECULAR INTERACTION ENERGIES; INTERMOLECULAR INTERACTIONS; LAYERED ARCHITECTURE; PHOSPHONATES; RADICAL CATIONS; SUBSEQUENT REDUCTION; TETRATHIAFULVALENES;

EID: 0000383892     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.19960021015     Document Type: Article
Times cited : (39)

References (70)
  • 1
    • 0037792824 scopus 로고
    • The layered compounds might have direct electronic functions such as metallic conductivity or superconductivity. See and leading references therein to the field of two-dimensional molecular conductors and superconductors
    • The layered compounds might have direct electronic functions such as metallic conductivity or superconductivity. See A. Pénicaud, K. Boubekeur, P. Batail, E. Canadell, P. Auban-Senzier, D. Jérôme, J. Am. Chem. Soc. 1993, 115, 4101, and leading references therein to the field of two-dimensional molecular conductors and superconductors.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 4101
    • Pénicaud, A.1    Boubekeur, K.2    Batail, P.3    Canadell, E.4    Auban-Senzier, P.5    Jérôme, D.6
  • 2
    • 0001538865 scopus 로고
    • The use of layered molecular compounds in electrooptics indirectly depends on their dielectric properties. See
    • The use of layered molecular compounds in electrooptics indirectly depends on their dielectric properties. See H. E. Katz, M. L. Schilling, Chem. Mater. 1993, 5, 1162.
    • (1993) Chem. Mater. , vol.5 , pp. 1162
    • Katz, H.E.1    Schilling, M.L.2
  • 3
    • 0003639836 scopus 로고
    • This is particularly true in the field of layered and pillared zirconium phosphonates: see Trans Tech, Aedermanndorf (Switzerland)
    • This is particularly true in the field of layered and pillared zirconium phosphonates: see Soft Chemistry Routes to New Materials (Eds.: J. Rouxel, M. Tournoux, R. Brec), Trans Tech, Aedermanndorf (Switzerland), 1994.
    • (1994) Soft Chemistry Routes to New Materials
    • Rouxel, J.1    Tournoux, M.2    Brec, R.3
  • 34
    • 84891337210 scopus 로고    scopus 로고
    • note
    • 2X series. We are currently attempting to grow single crystals of this very interesting compound.
  • 36
    • 84891326162 scopus 로고    scopus 로고
    • note
    • b) this is also consistent with our observations that the methanol hydrolysis of 3 under strictly anaerobic conditions (sealed evacuated tube) does not produce the black paramagnetic compound 5 but an extremely air-sensitive orange product instead.
  • 47
    • 33746305431 scopus 로고
    • English translation from
    • English translation from Zh. Org. Khim. 1986, 22, 2372.
    • (1986) Zh. Org. Khim. , vol.22 , pp. 2372
  • 52
    • 84891302885 scopus 로고    scopus 로고
    • note
    • Conventionally, when the highest occupied molecular orbital (HOMO) of a molecule is filled with just one electron it is referred to as SOMO (singly occupied molecular orbital). However, in order to facilitate the comparison of 7 with other π-donors of the TTF family we still refer to it as HOMO.
  • 54
    • 85050430112 scopus 로고
    • Since overlap is explicitly included in extended Hückel calculations, these interaction energies should not be confused with the conventional transfer integrals. Although the two quantities are obviously related and have the same physical meaning, the absolute values of the interaction energies are somewhat larger than those of the transfer integrals
    • b) J. M. Williams, H. H. Wang, T. J. Emge, U. Geiser, M. A. Beno, P. C. W. Leung, K. D. Carlson, R. Thorn, A. J. Schultz, Prog. Inorg. Chem. 1987, 35, 51. Since overlap is explicitly included in extended Hückel calculations, these interaction energies should not be confused with the conventional transfer integrals. Although the two quantities are obviously related and have the same physical meaning, the absolute values of the interaction energies are somewhat larger than those of the transfer integrals.
    • (1987) Prog. Inorg. Chem. , vol.35 , pp. 51
    • Williams, J.M.1    Wang, H.H.2    Emge, T.J.3    Geiser, U.4    Beno, M.A.5    Leung, P.C.W.6    Carlson, K.D.7    Thorn, R.8    Schultz, A.J.9
  • 68
    • 84891338272 scopus 로고    scopus 로고
    • note
    • Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-1220-22. Copies of the data can be obtained free of charge on application to the Director, CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: int. code + (1223) 336-033; e-mail: teched@chemcrys.cam.ac.uk).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.