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CR. Nevertheless, it is easy to show that the change in the gap between two different solvents is negligible.
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2642704562
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note
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Expression 4 is based on the assumptions that the conjugation paths for the unpaired electrons are restricted to a flat moiety, where the expectation value of the ZFS parameter, D, is approximated into a two-dimensional frame of reference. For details, see ref 13 and refs 38 and 39 therein.
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33
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35
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2642615709
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note
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In some cases, phase inversion indicating a change from singlet-into triplet-initiated spectra is noticed only by the spectral line shape, and not by the kinetic traces. This occurs when the ratio between the two respective spectra exceeds the value of 1:5. In these cases the kinetic trace is dominated by the stronger component (see also Table 4).
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