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For preliminary results with uracil derivatives, see: R. Boese, J. Rodriguez, K. P. C. Vollhardt, Angew. Chem. 1991, 103, 1032; Angew. Chem. Int. Ed. Engl. 1991, 30, 993; details of the crystal structure investigation can be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen (Germany), (fax: (+ 49)7247-808-666; e-mail: crysdata@fiz.karlsruhe.de) on quoting the depository number CSD-320197.
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For preliminary results with uracil derivatives, see: R. Boese, J. Rodriguez, K. P. C. Vollhardt, Angew. Chem. 1991, 103, 1032; Angew. Chem. Int. Ed. Engl. 1991, 30, 993; details of the crystal structure investigation can be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen (Germany), (fax: (+ 49)7247-808-666; e-mail: crysdata@fiz.karlsruhe.de) on quoting the depository number CSD-320197.
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3N in THF (see the Experimental Section).
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A similar formal C-H activation has been observed for furans, see ref. [6].
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85034534576
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We cannot rule out an alternative mechanism that involves a Diels-Alder addition of a coordinated alkene to the diene moiety of the cobaltacyclopentadiene intermediate.
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