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Volumn 32, Issue 17, 1999, Pages 5681-5688

Calculating phase diagrams of polymer-platelet mixtures using density functional theory: implications for polymer/clay composites

Author keywords

[No Author keywords available]

Indexed keywords

CLAY; LIQUID CRYSTALS; MIXTURES; MOLECULAR DYNAMICS; MORPHOLOGY; PHASE DIAGRAMS; PHASE TRANSITIONS; POLYMERS; PROBABILITY DENSITY FUNCTION; THERMODYNAMICS;

EID: 0032598408     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma990135t     Document Type: Article
Times cited : (138)

References (56)
  • 13
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    • Vaia, R. A.; Giannelis, E. P. Macromolecules 1997, 30, 7990; 1997, 30, 8000.
    • (1997) Macromolecules , vol.30 , pp. 8000
  • 20
    • 0032325313 scopus 로고    scopus 로고
    • and references therein
    • Gast, A. P.; Russel, W. B. Phys. Today 1998, 12, 24 and references therein.
    • (1998) Phys. Today , vol.12 , pp. 24
    • Gast, A.P.1    Russel, W.B.2
  • 30
    • 0000195684 scopus 로고
    • Chiu, H.-W.; Kyu, T. J. Chem. Phys. 1995, 103, 7471; Phys. Rev. E 1996, 53, 3618; J. Chem. Phys. 1997, 107, 6859.
    • (1995) J. Chem. Phys. , vol.103 , pp. 7471
    • Chiu, H.-W.1    Kyu, T.2
  • 31
    • 0000042689 scopus 로고    scopus 로고
    • Chiu, H.-W.; Kyu, T. J. Chem. Phys. 1995, 103, 7471; Phys. Rev. E 1996, 53, 3618; J. Chem. Phys. 1997, 107, 6859.
    • (1996) Phys. Rev. E , vol.53 , pp. 3618
  • 32
    • 0343073605 scopus 로고    scopus 로고
    • Chiu, H.-W.; Kyu, T. J. Chem. Phys. 1995, 103, 7471; Phys. Rev. E 1996, 53, 3618; J. Chem. Phys. 1997, 107, 6859.
    • (1997) J. Chem. Phys. , vol.107 , pp. 6859
  • 46
    • 0345407501 scopus 로고    scopus 로고
    • note
    • int is small can be satisfied if there is an effective adsorption of chains on the clay surface. Here, the losses in the conformational entropy are balanced by the gains in enthalpy. For more details on the calculation of the free energy of adsorbing chains between the two surfaces, see refs 35 and 36.
  • 49
    • 0344545207 scopus 로고    scopus 로고
    • note
    • Calculations are performed on a Silicon Graphics workstation Indy R6000; one run takes approximately 1 h of CPU time.
  • 53
    • 6744244931 scopus 로고
    • de Miguel, E.; Rull, L. F.; Chalam, M. K.; Gubbins, K. E.; van Swol, F. Mol. Phys. 1991, 72, 593; 1991, 74, 405.
    • (1991) Mol. Phys. , vol.74 , pp. 405


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.