Multiphase chemistry of NO3 in the remote troposphere

Journal of Geophysical Research Atmospheres

Volumn 103, Issue D13, 1998, Pages 16133-16143

  Rudich, Y ^a,b   Talukdar, R K ^a,c   Ravishankara, A R ^a,c  

^a NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

^b WEIZMANN INSTITUTE OF SCIENCE   (Israel)

^c UNIVERSITY OF COLORADO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; MARINE ATMOSPHERE; NITRATE; TROPOSPHERE;

EID: 0032551827     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/98JD01280     Document Type: Article

References (58)

1. 5 with NaCl solution: Bulk and aerosol experiments, J. Geophys. Res., 102, 3795-3804, 1997.
2. 3 radicals with DMS in coastal air, Proc. Soc. Photo. Opt. Instrum. Eng., 1715-24, 1-10, 1990.
3. Carslaw, N., J.M.C. Plane, H. Coe, and E. Cuevas, Observations of the nitrate radical in the free troposphere at Izana de Tenerife, J. Geophys. Res., 102, 10613-10622, 1997.
4. 3 in the nighttime chemistry of a cloud, J. Geophys. Res., 91, 5331-5337, 1986a.
5. 3 in the nighttime chemistry of a cloud," J. Geophys. Res., 91, 14,571-14,572, 1986b.
6. Chameides, W.L., and D.D. Davis, The free radical chemistry of cloud droplets and its impact upon the composition of rain, J. Geophys. Res., 87, 4863-4877, 1982.
7. Chameides, W.L., and A.W. Stelton, Aqueous-phase chemical processes in deliquescent sea-salt aerosols: A mechanism that couples the atmospheric cycles of S and sea salt, J. Geophys. Res., 97, 20565-20580, 1992.
8. 2- in aqueous solution, J. Phys. Chem., 94, 2191-2198, 1990.
9. DeMore, W.B., S.P. Sander, D.M. Golden, R.F. Hampson, M.J. Kurylo, C.J. Howard, A.R. Ravishankara, C.E. Kolb, and M.J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling, Evaluation 11, JPL Publ., 94-26, 1994.
10. Eigen, M., and K. Kustin, The kinetics of halogen hydrolysis, J. Am. Chem. Soc., 84, 1355-1361, 1962.
11. Exner, M., H. Hermann, and R. Zellner, Laser-based studies of reactions of the nitrate radical in aqueous solution, Ber. Bunsenges. Phys. Chem., 96, 470-477, 1992.
12. Fan, S.-M., and D.J. Jacob, Surface ozone depletion in Arctic spring sustained by bromine reactions on aerosols, Nature, 359, 522-524, 1992.
13. Fogelman, K.D., D.M. Walker, and D.W. Margerum, Non-metal redox kinetics: Hypochlorite and hypochlorus acid reactions with sulfite, Inorg. Chem., 28, 986-993, 1989.
14. 5 by water and NaCl solutions, J. Phys. Chem., 98, 8780-8784, 1994.
15. Graedel, T.E., and K.I. Goldberg, Kinetic studies of raindrop chemistry, 1, Inorganic and organic processes, J. Geophys. Res., 88, 10865-10882, 1983.
16. Haag, W.R., and J. Hoigne, Ozonation of bromide-containing waters: Kinetics of formation of hypobromous acid and bromate, Environ. Sci. Technol., 17, 261-267, 1983.
17. 2 radical uptake coefficients on water and sulfuric acid surfaces, J. Phys. Chem., 96, 4979-4985, 1992.
18. Heikes, B., M. Lee, D. Jacob, R. Talbot, J. Bradshaw, H.B. Singh, D. Blake, B. Anderson, H. Fuelberg, and A.M. Thompson, Ozone, hydroperoxides, oxides of nitrogen, and hydrocarbon budgets in the marine boundary layer over the South Atlantic, J. Geophys. Res., 101, 24221-24234, 1996.
19. Huebert, B.J., S. Howell, P. Laj, J.E. Johnson, T.S. Bates, P.K. Quinn, V. Yerogov, A.D. Clarke, and J.N. Porter, Observations of the atmospheric sulfur cycle on SAGA 3, J. Geophys. Res., 98, 16985-16995, 1993.
20. Huie, R.E., Free radical chemistry of the atmospheric aqueous phase, in Progress and Problems in Atmospheric Chemistry, edited by J.R. Barker, pp. 374-419, World Sci., Singapore, 1995.
21. - in aqueous solutions, J. Phys. Chem., 88, 5665-5669, 1984.
22. Huie, R.E., and P. Neta, Rate constants for some oxidation of S(IV) by radicals in aqueous solutions, Atmos. Environ., 21, 1743-1747, 1987.
23. 3 on water solutions: Rate coefficients for reaction with cloud water constituents, J. Phys. Chem., 101, 2316-2322, 1997.
24. Jacob, D.J., Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate, J. Geophys. Res., 91, 9807-9826, 1986.
25. (aq) by aqueous droplets, J. Geophys. Res., 95, 20559-20563, 1990.
26. Jensen, T.L., S.M. Kreidenweis, Y. Kim, H. Sievering, and A. Pszenny, Aerosol distribution in the North Atlantic marine boundary layer during Atlantic Stratocumulus Transition Experiment/ Marine Aerosol and Gas Exchange, J. Geophys. Res., 101, 4455-4467, 1996.
27. 6 hydrocarbons during the Polar Sunrise 1992 Experiment: Evidence for Cl atom and Br atom chemistry, J. Geophys. Res., 99, 25355-25368, 1994.
28. Lelieveld, J., and P.J. Crutzen, The role of clouds in tropospheric chemistry, J. Atmos. Chem., 12, 229-267, 1991.
29. Lovejoy, E.R., and D.R. Hanson, Measurement of the kinetics of reactive uptake by submicron sulfuric acid particles, J. Phys. Chem., 99, 2080-2087, 1995.
30. Malleson, A.M., H.M. Kellet, R.G. Myhill, and W.P. Sweetenham, FACSIMILE user guide, Publ. R 13729, A.E.R.E. Publ. Off., Oxfordshire, England, 1990.
31. Mihelcic, D., D. Klemp, P. Musgen, A.W. Patz, and A. Voltz-Thomas, Simultaneous measurements of peroxy and nitrate radicals at Schauinsland, J. Atmos. Chem., 16, 313-335, 1993.
32. 3 in the nighttime chemistry of a cloud," J. Geophys. Res., 91, 14,569-14,570, 1986.
33. Mozurkewich, M., Mechanisms for the release of halogens from sea salt particles by free radical reactions, J. Geophys. Res., 100, 14,199-14,207, 1995.
34. Penkett, S.A., B.M.R. Jones, K.A. Brice, and A.E.J. Eggleton, The importance of atmospheric ozone and hydrogen peroxide in oxidizing sulfur dioxide in cloud and rainwater, Atmos. Environ., 13, 123-137, 1979.
35. Penkett, S.A., B.J. Bandy, C.E. Reeves, D. McKenna, and P. Hignett, Measurements of peroxides in the atmosphere and their relevance to the understanding of global tropospheric chemistry, Faraday Discuss., 100, 155-174, 1995.
36. Platt, U.F., A.W. Winer, H.W. Bierman, R. Atkinson, and J.N. Pitts Jr., Measurement of nitrate radical concentrations in continental air, Environ. Sci. Technol., 18, 365-369, 1984.
37. 5 by sulfuric acid solutions, J. Geophys. Res., 102, 3583-3601, 1997.
38. Rock, P.A., Chemical Thermodynamics, Univ. Sci. Books, Mill Valley, Calif, 1983.
39. 3 on pure water and ionic solutions, J. Geophys. Res., 101, 21023-21031, 1996a.
40. 3 by measuring its uptake on KI solutions, Chem. Phys. Lett., 261, 467, 1996b.
41. Russel, L.M., B.J. Huebert, R.C. Flagan, and J.H. Seinfeld, Characterization of submicron aerosol size distributions from time resolved measurements in the Atlantic Stratocumulus Transition Experiment/ Marine Aerosol and Gas Exchange, J. Geophys. Res., 101, 4469-4478, 1996.
42. Sander, R., and P.J. Crutzen, Model study indicating halogen activation and ozone destruction in polluted air masses transported to the sea, J. Geophys. Res., 101, 9121-9138, 1996.
43. Sander, R., J. Lelieveld, and P.J. Crutzen, Modeling of the nighttime nitrogen and sulfur chemistry in size resolved droplets of an orographic cloud, J. Atmos. Chem., 20, 89-116, 1995.
44. Sauer, F., S. Limbach, and G.K. Moortgat, Measurements of hydrogen peroxide and individual organic peroxides in marine troposphere during Fieldvoc Campaign, in Physico-Chemical Behavior of Atmospheric Pollutants, edited by G. Angeletti, and G. Restelli, pp. 245-251, Eur. Comm., Varese, Italy, 1993.
45. 2 in liquid water clouds, J. Geophys. Res., 89, 11589-11598, 1984.
46. Schwartz, S.E., Mass-transport considerations pertinent to aqueous phase reactions of gases in liquid-water Clouds, Chemistry of Multiphase Atmospheric Systems, edited by W. Jaeschke, NATO ASI Ser., G6, pp. 415-471, Springer-Verlag, Berlin, 1986.
47. Schwartz, S.E., and W.H. White, Solubility equilibria of the nitrogen oxides and oxyacids in dilute aqueous solution, in Advances in Environmental Science and Technology, edited by J.R. Pfafflin, and E.N. Ziegler, pp. 1-45, Gordon and Breach, New York, 1981.
48. Sievering, H., E. Gorman, T. Ley, A. Pszenny, M. Springer-Young, J. Boatman, Y. Kim, C. Nagamoto, and D. Wellman, Ozone oxidation of sulfur in sea-salt aerosol particles during the Azores Marine Aerosol and Gas Exchange Experiment, J. Geophys. Res., 100, 23075-23081, 1995.
49. Singh, H.B., Halogens in the atmospheric environment, in Composition, Chemistry and Climate of the Atmosphere, edited by H.B. Singh, pp. 216-249, Van Norstand Reinhold, New York, 1995.
50. Singh, H.B., G.L. Gregory, B. Anderson, E. Browell, G.W. Sachse, D.D. Davis, J. Crawford, J.D. Bradshaw, R. Talbot, D.R. Blake, D. Thornton, R. Newell, and J. Merrill, Low ozone in the marine boundary layer of the tropical Pacific Ocean: Photochemical loss, chlorine atoms and entrainment, J. Geophys. Res., 101, 1907-1917, 1996.
51. Slemr, F., and H.G. Tremmel, Hydroperoxides in the marine troposphere over the Atlantic, J. Atmos. Chem., 19, 371-404, 1994.
52. 3 -Radikalen mit wassrigen Losungen: Bestimmung des Henry- und Massenakkommodationskoeffizienten, Ph.D. thesis, Univ. of Wuppertal, Wuppertal, Germany, 1992.
53. 3 radicals with aqueous solutions: Solubility and sticking coefficient, J. Atmos. Chem., 29, 17-43, 1998.
54. Troy, R.C., and D.W. Magerum, Non-metal redox kinetics: Hypobromite and hypobromous acid reactions with iodide and with sulfite and the hydrolysis of bromosulfate, Inorg. Chem., 30, 3538-3543, 1991.
55. Vogt, R., P.J. Crutzen, and R. Sander, A mechanism for halogen release from sea-salt aerosol in the remote marine boundary layer, Nature, 383, 327-330, 1996.
56. Wang, T.X., and D.W. Margerum, Kinetics of reversible chlorine hydrolysis: Temperature dependence and general-acid /base-assisted mechanisms, Inorg. Chem., 33, 1050-1055, 1994.
57. Wayne, R.P., I. Barnes, P. Biggs, J.P. Burrows, C.E. Canosa-Mas, J. Hjorth, G. Le Bras, G.K. Moortgat, D. Perner, G. Poulet G. Restelli, and H. Sidebottom, The nitrate radical: Physics, chemistry and the atmosphere, Atmos. Environ., 25A, 1-203, 1991.
58. Weast, R.C., (Ed.), CRC Handbook of Chemistry and Physics, CRC Press, Boca Raton, Fla., 1980.