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The silyl-protected adducts are the predominant product in all of the addition reactions. Small amounts of the free alcohol products could also be isolated albeit in 5-10% yields. The % ee value of the alcohol product was found to be equal to that of the silyl-protected adduct for each of the aldehydes examined.
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32
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85032998694
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note
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2 solution works well in the addition reaction and obviates the need to remove the bulk acetonitrile solvent.
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