Continuous self-assembly of organic-inorganic nanocomposite coatings that mimic nacre

Nature

Volumn 394, Issue 6690, 1998, Pages 256-260

  Sellinger, Alan ^a   Weiss, Pilar M ^a   Nguyen, Anh ^a   Lu, Yunfeng ^a   Assink, Roger A ^a   Gong, Weiliang ^b   Brinker, C Jeffrey ^a  

^a SANDIA NATIONAL LABORATORIES   (United States)

^b UNIVERSITY OF NEW MEXICO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIOPOLYMER; CALCIUM CARBONATE; METHACRYLIC ACID DERIVATIVE; MONOMER; POLY(DODECYL METHACRYLATE); SILICON DIOXIDE; SURFACTANT; UNCLASSIFIED DRUG;

ARTICLE; INFRARED SPECTROSCOPY; MICELLE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; PRIORITY JOURNAL;

EID: 0032537735     PISSN: 00280836     EISSN: None     Source Type: Journal    
DOI: 10.1038/28354     Document Type: Article

References (30)

1. Jackson, A., Vincent, J. & Turner, R. The mechanical design of nacre. Proc. R. Soc. Lond. B 234, 415-425 (1988).
2. Aksay, I. et al. Biomimetic pathways for assembling inorganic thin films. Science 273, 892-898 (1996).
3. Bunker, B. et al. Ceramic thin-film formation on functionalized interfaces through biomimetic processing. Science 264, 48-55 (1994).
4. Heuer, A. et al. Innovative materials processing strategies: a biomimetric approach. Science 255, 1098-1105 (1992).
5. Mann, S. Molecular tectonics in biomineralization and biomimetics materials chemistry. Nature 365, 499-505 (1993).
6. Lu, Y. et al. Continuous formation of supported cubic and hexagonal mesoporous films by sol-gel dip-coating. Nature 389, 364-368 (1997).
7. Kresge, C., Leonowicz, M., Roth, W., Vartuli, C. & Beck, J. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 359, 710-712 (1992).
8. Heywood, B. & Mann, S. Template-directed nucleation and growth of inorganic materials. Adv. Mater. 6, 9-19 (1994).
9. Tarasevich, B., Rieke, P. & Liu, J. Nucleation and growth of oriented ceramic films onto organic interfaces. Chem. Mater. 8, 292-300 (1996).
10. Yang, H., Kuperman, A., Coombs, N., Mamiche-Afara, S., Ozin, G. Synthesis of oriented films of mesoporous silica on mica. Nature 379, 703-705 (1996).
11. Keller, S., Kim, H. & Mallouk, T. Layer-by-layer assembly of intercalation compounds and heterostructures on surfaces: toward molecular "beaker" epitaxy. J. Am. Chem. Soc. 116, 8817-8818 (1994).
12. Ogawa, M. Formation of novel oriented transparent films of layered silica-surfactant nanocomposites. J. Am. Chem. Soc. 116, 7941-7942 (1994).
13. Okada, H., Sakata, K. & Kunitake, T. Formation of oriented iron oxide particles in cast multibilayer films. Chem. Mater. 2, 91-93 (1990).
14. Tanev, P. & Pinnavaia, T. Biomimetic templating of porous lamellar silicas by vesicular surfactant assemblies. Science 271 1267-1269 (1996).
15. Burkett, S., Sims, S. & Mann, S. Synthesis of hybrid inorganic-organic mesoporous silica by co-condensation of siloxane and organosiloxane precursors. Chem. Commun. 11, 1367-1368 (1996).
16. Brinker, C., Sehgal, R., Raman, N., Schunk, P. & Headley, T. Polymer approach to supported silica membranes. J. Sol-Gel Sci. Technol. 2, 469-476 (1994).
17. Pretsch, E., Siebl, J., Simon, W. & Clerc, T. in Tables of Spectral Data for Structure Determination of Organic Compounds (eds Pretsch, E., Siebl, J., Simon, W. & Clerc, T.) 1141-1142 (Springer, Berlin, 1989).
18. Yang, H., Coombs, N., Dag, O., Sokolov, I. & Ozin, G. Free-standing mesoporous silica films; morphogenesis of channel and surface patterns. J. Mater. Chem. 7, 1755-1761 (1997).
19. Giannelis, E. Polymer layered silicate nanocomposites. Adv. Mater. 8, 29-35 (1996).
20. Gray, D., Hu, S., Juang, E. & Gin, D. Highly ordered polymer-inorganic nanocomposites via monomer self-assembly: in situ condensation approach. Adv. Mater. 9, 731-736 (1997).
21. Templin, M. et al. Organically-modified aluminosilicate mesostructures from block-copolymer phases. Science 278, 1795-1798 (1997).
22. Huber, C., Moller, K. & Bein, T. Reactivity of a trimethylstannyl molybdenum complex in mesoporous MCM-41. J. Chem. Soc. 2619-2620 (1994).
23. Wu, C. & Bein, T. Conducting polyaniline filaments in a mesoporous channel host. Science 264, 1757-1759 (1994).
24. Ozin, G. Nanochemistry: synthesis in diminishing dimensions. Adv. Mater. 4, 612-649 (1992).
25. Nishida, F. et al. In situ fluorescence probing of the chemical changes during sol-gel thin film formation. J. Am. Ceram. Soc. 78, 1640-1648 (1995).
26. Manne, S., Cleveland, J., Gaub, H., Stucky, G. & Hansma, P. Direct visualization of the surfactant hemimicelles by force microscopy of the electrical double layer. Langmuir 10, 4409-4413 (1994).
27. Bull, L. et al. in Zeolites and Related Microporous Materials: State of the Art 1994 (eds Weitkamp, J., Karge, H., Pfeifer, H. & Holderich, W.) 429-434 (Elsevier, Amsterdam, 1994).
28. Israelachvili, J. Intermolecular and Surface Forces (Academic, San Diego, 1992).
29. Odian, G. Principles of Polymerization (Wiley, New York, 1981).
30. Yang, H., Coombs, N., Sokolov, I. & Ozin, G. Free-standing and oriented mesoporous silica films grown at the air-water interface. Nature 381, 589-592 (1996).