CsF in organic synthesis. The first and convenient synthesis of enantiopure bisoprolol by use of glycidyl nosylate

Tetrahedron Letters

Volumn 39, Issue 20, 1998, Pages 3173-3176

  Kitaori, Kazuhiro ^a   Furukawa, Yoshiro ^a   Yoshimoto, Hiroshi ^a   Otera, Junzo ^b  

^a Daiso Co Ltd   (Japan)

^b OKAYAMA UNIVERSITY OF SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BETA 1 ADRENERGIC RECEPTOR BLOCKING AGENT; BISOPROLOL; CESIUM; FLUORIDE; PHENOL DERIVATIVE;

ARTICLE; CATALYSIS; DRUG SYNTHESIS; ENANTIOMER; RACEMIC MIXTURE; STEREOCHEMISTRY;

EID: 0032516333     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)00452-3     Document Type: Article

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20. 3 in acetone or NaH in DMF gave the aryl glycidyl ether in 38% yield (93.8 %ee) or 60% yield (97.6 %ee).