Palladium alkoxides: Potential intermediacy in catalytic amination, reductive elimination of ethers, and catalytic etheration. Comments on alcohol elimination from Ir(III)

Journal of the American Chemical Society

Volumn 118, Issue 51, 1996, Pages 13109-13110

  Mann, Grace ^a   Hartwig, John F ^a  

^a YALE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINE; ETHER; METAL OXIDE; PALLADIUM;

ARTICLE; CATALYSIS; DRUG SYNTHESIS; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS;

EID: 0030466983     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963273w     Document Type: Article

References (21)

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2. Driver, M. S.; Hartwig, J. F. J. Am. Chem. Soc. 1995, 117, 4708-4709.
3. For an example of oxidatively induced reductive elimination from Ni(II) see: (a) Koo, K.; Hillhouse, G. L. Organometallics 1995, 14, 4421-4423. (b) Koo, K.; Hillhouse, G. L.; Rheingold, A. L. Organometallics 1995, 14, 456.
4. For an example of oxidatively induced reductive elimination from Ni(II) see: (a) Koo, K.; Hillhouse, G. L. Organometallics 1995, 14, 4421-4423. (b) Koo, K.; Hillhouse, G. L.; Rheingold, A. L. Organometallics 1995, 14, 456.
5. Baranano, D.; Hartwig, J. F. J. Am. Chem. Soc. 1995, 117, 2937-2938.
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7. Driver, M. S.; Hartwig, J. F. J. Am. Chem. Soc. 1996, 118, 7217-7218.
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10. Louie, J.; Driver, M. S.; Hamann, B. C.; Hartwig, J. F. Submitted for publication.
11. Bryndza, H. E.; Tam, W. Chem. Rev. 1988, 88, 1163-1188.
12. Thompson, J. S.; Randall, S. L.; Atwood, J. D. Organometallics 1991, 10, 3906-3910.
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14. Matsunaga, P. T.; Mavropoulous, J. C.; Hillhouse, G. L. Polyhedron 1995, 14, 175-185.
15. A palladium-catalyzed cyclization to form oxygen heterocycles has now been reported: Palucki, M.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1996, 118, 10333.
16. 1H NMR spectroscopy and GC/MS.
17. Driver, M. S.; Hartwig, J. F. J. Am. Chem. Soc. 1996, 118, 4206-4207.
18. Hartwig, J. F.; Richards, S.; Baranano, D.; Paul, F. J. Am. Chem. Soc. 1996, 118, 3626-3633.
19. DPPE = 1,2-bis(diphenylphosphino)ethane, BINAP = 2,2′-bis-(diphenylphosphino)-1,1′-binaphthyl, DPPP = 1,2-bis(diphenylphosphino)-propane, DPPBz = 1,2-bis(diphenylphosphino)benzene.
20. Reed, C. A.; Roper, W. R. J. Chem. Soc., Chem. Commun. 1973, 1370.
21. No unusual structural features were observed. Data are provided as Supporting Information.