An analysis of cobaloxime chemistry with the electrostatic-covalent model

Journal of Organometallic Chemistry

Volumn 512, Issue 1-2, 1996, Pages 61-68

  Drago, Russell S ^a  

^a University of Florida ^*  (United States)

Author keywords

Cobalt; Electrostatic covalent model; Oximes

Indexed keywords

EID: 0030593224     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(95)05882-P     Document Type: Article

References (23)

1. [1] R.S. Drago, Inorg. Chem., 29, (1990) 1186.
2. [2] (a) R.S. Drago, and A.P. Dadmun, J. Am. Chem. Soc., 115 (1993) 8592;
3. (b) R.S. Drago and A.P. Dadmun, J. Am. Chem. Soc., 116 (1994) 1792;
4. (c) R.S. Drago, and J.A. Zoltewicz, J. Org. Chem., 59 (1994) 2824.
5. [3] (a) R.S. Drago, "Applications of Electrostatic-Covalent Models in Chemistry" Surfside Scientific, P.O. Box 13413, Gainesville, FL 32604, 1995;
6. (b) R.S. Drago, and G.C. Vogel, J. Am. Chem. Soc., 57 (1992) 9527;
7. (c) See R.S. Drago Coord. Chem. Rev., 33 (1980) 251 for a discussion of this model.
8. [4] R.S. Drago, Inorg. Chem., 34 (1995) 3543.
9. [5] R.S. Drago, Organometallics, 14 (1995) 3408.
10. [6] (a) N. Bresciani-Pahor, M. Forcolin, L.G. Marzilli, L. Randaccio, M.F. Summers, and P.J. Toscano, Coord. Chem. Rev., 63 (1985) 1 and references cited therein;
11. (b) L.G. Marzilli, F. Bayo, M.F. Summers, L.B. Thomas, E. Zangrando, N. Bresciani-Pahor, M. Mari, and L. Randaccio, J. Am. Chem. Soc. 109 (1987) 6045.
12. [7] (a) K.L. Brown, and S. Salyanarayana, J. Am. Chem. Soc., 114 (1992) 564 and references cited therein;
13. (b) K.L. Brown, and A.W. Awtrey, Inorg. Chem., 17 (1978) 111;
14. (c) K.L. Brown, D. Lyles, M. Pencovice, and R.G. Kallen, J. Am. Chem. Soc., 97 (1975) 7338.
15. [8] R.S. Drago, J.A. Nusz, and M.S. Nozari, Inorg. Chem., 12 (1973) 2809;
16. (c) K.L. Brown, D. Lyles, M. Pencovice and R.G. Kallen, J. Am. Chem. Soc., 97 (1975) 7338.
17. [8] R.S. Drago, J.A. Nusz, and M.S. Nozari, Inorg. Chem., 12 (1973) 2809.
18. [9] C. Bied-Charreton, and A. Gaudemer, TeH. Lett., (1969) 4189.
19. [10] (a) B.E. Reichert, B.O. West, J. Chem. Soc., Chem. Commun., (1974) 177;
20. (b) R.A. La Rossa, and T.L. Brown, J. Am. Chem. Soc., 96 (1974), 2072.
21. [11] J. Halpern, and P.F. Phelan, J. Am. Chem. Soc., 94 (1972) 1881.
22. [12] G. Costa, A. Puxeddu, C. Tavagnacco, and R. Dreas Garlatti, Inorg. Chim. Acta 89 (1984) 65.
23. [13] P.E. Doan, and R.S. Drago, J. Am. Chem. Soc., 106 (1984) 2772. This reference shows linear free energy relations do not have to give a linear plot of - ΔH vs. ΔS. They are ones in which both - ΔH and ΔS fit Eq. (1).