Controlled/"living" radical polymerization applied to water-borne systems

Macromolecules

Volumn 31, Issue 17, 1998, Pages 5951-5954

  Gaynor, Scott G ^a   Qiu, Jian ^a   Matyjaszewski, Krzysztof ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COAGULATION; COMPOSITION EFFECTS; COPPER; EMULSION POLYMERIZATION; INITIATORS (CHEMICAL); MOLECULAR WEIGHT DISTRIBUTION; POLYETHYLENE GLYCOLS; POLYMETHYL METHACRYLATES; POLYSTYRENES; REACTION KINETICS; SURFACE ACTIVE AGENTS; THERMAL EFFECTS;

ATOM TRANSFER RADICAL POLYMERIZATION; BRIJ SURFACTANTS;

FREE RADICAL POLYMERIZATION;

EID: 0032138977     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma980724j     Document Type: Article

References (21)

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21. General procedure for polymerization: To a round-bottom flask with stir bar, were added copper(I) bromide, ligand, and surfactant. The contents of the flask were degassed by applying vacuum and backfilling with nitrogen. Degassed monomer and water were added to the flask via syringe. The mixture was stirred until the surfactant dissolved and an emulsified mixture was obtained. The reaction was heated to the desired reaction temperature and the initiator added. Upon completion of the polymerization, the copper complex was removed by addition of an ion-exchange resin (Dowex MSC-1), stirring and filtration of the resin.