Scanning electrochemical microscopy (SECM) as a probe of transfer processes in two-phase systems: Theory and experimental applications of SECM-induced transfer with arbitrary partition coefficients, diffusion coefficients, and interfacial kinetics

Journal of Physical Chemistry B

Volumn 102, Issue 9, 1998, Pages 1586-1598

  Barker, Anna L ^a   Macpherson, Julie V ^a   Slevin, Christopher J ^a   Unwin, Patrick R ^a  

^a UNIVERSITY OF WARWICK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

DIFFUSION IN LIQUIDS; ELECTROLYSIS; HYDROGELS; MATHEMATICAL MODELS; MICROELECTRODES; MICROSCOPIC EXAMINATION; PHASE EQUILIBRIA; PHASE SEPARATION; REACTION KINETICS; SOLUTIONS;

PARTITION COEFFICIENTS; SCANNING ELECTROCHEMICAL MICROSCOPY INDUCED TRANSFER (SECMIT);

PHASE INTERFACES;

EID: 0031998866     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp973370r     Document Type: Article

References (63)

1. (a) Bard, A. J.; Fan, F.-R.; Pierce, D. T.; Unwin, P. R.; Wipf, D. O.; Zhou. F. Science 1991, 254, 68.
2. (b) Bard, A. J.; F.-R. Fan. Faraday Discuss. 1992, 94, 1.
3. (c) Bard, A. J.; Mirkin, M. V.; Fan, F.-R. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1993; Vol. 18, p 243.
4. (d) Arca, M.; Bard, A. J.; Horrocks, B. R.; Richards, T. C.; Treichel, D. A. Analyst 1994, 119, 719.
5. (e) Mirkin, M. V. Anal. Chem. 1996, 68, 177A.
6. Wipf, D. O.; Bard, A. J. J. Electrochem. Soc. 1991, 138, 469.
7. (a) Bard, A. J.; Mirkin, M. V.; Unwin, P. R.; Wipf, D. O. J. Phys. Chem. 1992, 96, 1861.
8. (b) Engstrom, R. C.; Small, B.; Kattan, L. Anal. Chem. 1992, 64, 241.
9. Wipf, D. O.; Bard, A. J. J. Electrochem. Soc. 1991, 138, L4.
10. Mirkin, M. V.; Bulhoes, L. O. S.; Bard, A. J. J. Am. Chem. Soc. 1993, 115, 201.
11. Engstrom, R. C.; Meaney, T.; Tople, R.; Wightman, R. M. Anal. Chem. 1987, 59, 2005.
12. Pierce, D. T.; Unwin, P. R.; Bard, A. J. Anal. Chem. 1992, 64, 1795.
13. Pierce, D. T.; Bard, A. J. Anal. Chem. 1993, 65, 3598.
14. (a) Mandler, D.; Bard, A. J. J. Electrochem. Soc. 1989, 136, 3143.
15. (b) Mandler, D.; Bard, A. J. J. Electrochem. Soc. 1990, 137, 1079.
16. (c) Meltzer, S.; Mandler, D. J. Electrochem. Soc. 1995, 142, L82.
17. (d) Wipf, D. O. Colloids Surf. A 1994, 93, 251.
18. (e) Macpherson, J. V.; Slevin, C. J.; Unwin, P. R. J. Chem. Soc., Faraday Trans. 1996, 92, 3799.
19. (a) Mandler, D.; Bard, A. J. J. Electrochem. Soc. 1990, 137, 2468
20. (b) Mandler, D.; Bard, A. J. Langmuir 1990, 6, 1489.
21. (a) Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. 1994, 98, 1704.
22. (b) Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. 1994, 98, 3109.
23. (c) Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. 1995, 99, 3338.
24. (d) Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. 1995, 99, 14824.
25. (e) Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. 1996, 100, 19475.
26. (f) Macpherson, J. V.; Hillier, A. C.; Unwin, P. R.; Bard, A. J. J. Am. Chem. Soc. 1996, 118, 6445.
27. Kranz, C.; Gaub, H. E.; Schuhmann, W. Adv. Mater. 1996, 8, 634.
28. Unwin, P. R.; Bard, A. J. J. Phys. Chem. 1992, 96, 5035.
29. Slevin, C. J.; Umbers, J. A.; Atherton, J. H.; Unwin, P. R. J. Chem. Soc., Faraday Trans. 1996, 92, 5177.
30. Wei, C.; Bard, A. J.; Mirkin, M. V. J. Phys. Chem. 1995, 99, 16033.
31. Solomon, T.; Bard, A. J. J. Phys. Chem. 1995, 99, 17487.
32. Tsionsky, M.; Bard, A. J.; Mirkin, M. V. J. Phys. Chem. 1996, 100, 17881.
33. Shao, Y.; Mirkin, M. V.; Rusling, J. F. J. Phys. Chem. B 1997, 101, 3202.
34. Unwin, P. R.; Slevin, C. J. Abstracts of the Fall Meeting of the Electrochemical Society, 1996; Vol. 96-2, p 810.
35. Slevin, C. J.; Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. B 1997, 101, 10851.
36. (a) Fan, F. R. F.; Bard, A. J. Science 1995, 267, 871.
37. (b) Fan, F. R. F.; Bard, A. J. Science 1995, 270, 1849.
38. Freiser, H. Chem. Rev. (Washington, D.C.) 1988, 88, 611.
39. Danesi, P. R.; Chiarizia, R. CRC Crit. Rev. Anal. Chem. 1980, 10, 1.
40. Atherton, J. H. Res. Chem. Kinet. 1994, 2, 19 3.
41. Girault, H. H.; Schiffrin, D. J. In Charge and Field Effects in Biosystems; Allen, M. J., Usherwood, P. N. R., Eds.; Abacus Press: Tunbridge Wells, 1984; p 17 1.
42. Ohkouchi, T.; Kakutani, T.; Senda, S. Bioelectrochem. Bioenerg. 1991, 25, 71, 81.
43. For a review, see, for example: Hanna, G. J.; Noble, R. D. Chem. Rev. (Washington, D.C.) 1985, 85, 583.
44. Saito, Y. Rev. Polarogr. 1968, 15, 177.
45. Unwin, P. R.; Bard, A. J. J. Phys. Chem. 1991, 95, 7814.
46. Bard, A. J.; Denuault, G.; Dornblaser, B. C.; Friesner. R. A.; Tuckerman, L. S. Anal. Chem. 1991, 63, 1282.
47. Kwak, J.; Bard, A. J. Anal. Chem. 1989, 61, 1221.
48. Shoup, D.; Szabo, A. J. Electroanal. Chem. 1982, 140, 237.
49. Winlove, C. P.; Parker, K. H.; Oxenham, R. C. J. Electroanal. Chem. 1984, 170, 293.
50. Denuault, G.; Mirkin, M. V.; Bard, A. J. J. Electroanal. Chem. 1991, 86, 27.
51. (a) Pyo, M.; Bard, A. J. Electrochim. Acta 1997, 42, 3077.
52. (b) Zhou, H., Che, G.; Dong, S. Electroanalysis 1997, 9, 41.
53. Kroschwitz, J. I. Encyclopedia of Polymer Science and Engineering, 2nd ed.; Wiley-Interscience: New York. 1985: Vol. 7, pp 783-807.
54. Pletcher, D.; Sotiropoulos. S. J. Electroanal. Chem. 1993, 356, 109.
55. Pletcher, D.; Sotiropoulos, S. J. Chem. Soc., Faraday Trans. 1995, 91, 457.
56. Macpherson, J. V.; O'Hare, D.; Unwin, P. R.; Winlove, C. P. Biophys. J. 1997, 73, 2771.
57. Luhring, P.; Schumpe, A. J Chem. Eng. 1989, 34, 250.
58. Schumpe, A.; Luhring, P. J. Chem. Eng. Data 1990, 35, 24.
59. (a) Albery, W. J.; Choudhery, R. A.; Fisk, P. R. Faraday Discuss. Chem. Soc. 1984, 77, 53.
60. (b) Albery, W. J.; Choudhery, R. A. J. Phys. Chem. 1988, 92, 1142.
61. Quickenden, T. I.; Qingzhong, X. J. Electrochem. Soc. 1996, 143, 1248.
62. (a) Lapidus, L.; Pinder, G. F. Numerical Solutions of Partial Differential Equations in Science and Engineering, Wiley: New York, 1982.
63. (b) Ames, W. F. Numerical Methods of Partial Differential Equations; Wiley: New York, 1977.