Measurement of local reactivity at liquid/solid, liquid/liquid, and liquid/gas interfaces with the scanning electrochemical microscope: Principles, theory, and applications of the double potential step chronoamperometric mode

Journal of Physical Chemistry B

Volumn 101, Issue 50, 1997, Pages 10851-10859

  Slevin, Christopher J ^a   Macpherson, Julie V ^a   Unwin, Patrick R ^a  

^a UNIVERSITY OF WARWICK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

DIFFUSION; ELECTROCHEMICAL ELECTRODES; ELECTROLYSIS; MATHEMATICAL MODELS; MICROELECTRODES; REACTION KINETICS; SOLUTIONS; SULFURIC ACID;

DOUBLE POTENTIAL STEP CHRONOAMPEROMETRY; SCANNING ELECTROCHEMICAL MICROSCOPY;

PHASE INTERFACES;

EID: 0031336494     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp972587i     Document Type: Article

References (63)

1. For reviews see, for example, the following. (a) Bard, A. J.; Fan, F.-R.; Pierce, D. T.; Unwin, P. R.; Wipf, D. O.; Zhou. F. Science 1991, 254, 68. (b) Bard, A. J.; Fan, F.-R. Faraday Discuss. 1992, 94, 1. (c) Bard, A. J.; Mirkin, M. V.; Fan, F.-R. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1993; Vol. 18, p 243. (d) Area, M.; Bard, A. J.; Horrocks, B. R.; Richards, T. C.; Treichel, D. A. Analyst 1994, 119, 719. (e) Unwin, P. R.; Macpherson, J. V. Chem. Ind. 1995, 874. (f) Mirkin, M. V. Anal. Chem. 1996, 177A.
2. For reviews see, for example, the following. (a) Bard, A. J.; Fan, F.-R.; Pierce, D. T.; Unwin, P. R.; Wipf, D. O.; Zhou. F. Science 1991, 254, 68. (b) Bard, A. J.; Fan, F.-R. Faraday Discuss. 1992, 94, 1. (c) Bard, A. J.; Mirkin, M. V.; Fan, F.-R. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1993; Vol. 18, p 243. (d) Area, M.; Bard, A. J.; Horrocks, B. R.; Richards, T. C.; Treichel, D. A. Analyst 1994, 119, 719. (e) Unwin, P. R.; Macpherson, J. V. Chem. Ind. 1995, 874. (f) Mirkin, M. V. Anal. Chem. 1996, 177A.
3. For reviews see, for example, the following. (a) Bard, A. J.; Fan, F.-R.; Pierce, D. T.; Unwin, P. R.; Wipf, D. O.; Zhou. F. Science 1991, 254, 68. (b) Bard, A. J.; Fan, F.-R. Faraday Discuss. 1992, 94, 1. (c) Bard, A. J.; Mirkin, M. V.; Fan, F.-R. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1993; Vol. 18, p 243. (d) Area, M.; Bard, A. J.; Horrocks, B. R.; Richards, T. C.; Treichel, D. A. Analyst 1994, 119, 719. (e) Unwin, P. R.; Macpherson, J. V. Chem. Ind. 1995, 874. (f) Mirkin, M. V. Anal. Chem. 1996, 177A.
4. For reviews see, for example, the following. (a) Bard, A. J.; Fan, F.-R.; Pierce, D. T.; Unwin, P. R.; Wipf, D. O.; Zhou. F. Science 1991, 254, 68. (b) Bard, A. J.; Fan, F.-R. Faraday Discuss. 1992, 94, 1. (c) Bard, A. J.; Mirkin, M. V.; Fan, F.-R. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1993; Vol. 18, p 243. (d) Area, M.; Bard, A. J.; Horrocks, B. R.; Richards, T. C.; Treichel, D. A. Analyst 1994, 119, 719. (e) Unwin, P. R.; Macpherson, J. V. Chem. Ind. 1995, 874. (f) Mirkin, M. V. Anal. Chem. 1996, 177A.
5. For reviews see, for example, the following. (a) Bard, A. J.; Fan, F.-R.; Pierce, D. T.; Unwin, P. R.; Wipf, D. O.; Zhou. F. Science 1991, 254, 68. (b) Bard, A. J.; Fan, F.-R. Faraday Discuss. 1992, 94, 1. (c) Bard, A. J.; Mirkin, M. V.; Fan, F.-R. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1993; Vol. 18, p 243. (d) Area, M.; Bard, A. J.; Horrocks, B. R.; Richards, T. C.; Treichel, D. A. Analyst 1994, 119, 719. (e) Unwin, P. R.; Macpherson, J. V. Chem. Ind. 1995, 874. (f) Mirkin, M. V. Anal. Chem. 1996, 177A.
6. For reviews see, for example, the following. (a) Bard, A. J.; Fan, F.-R.; Pierce, D. T.; Unwin, P. R.; Wipf, D. O.; Zhou. F. Science 1991, 254, 68. (b) Bard, A. J.; Fan, F.-R. Faraday Discuss. 1992, 94, 1. (c) Bard, A. J.; Mirkin, M. V.; Fan, F.-R. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1993; Vol. 18, p 243. (d) Area, M.; Bard, A. J.; Horrocks, B. R.; Richards, T. C.; Treichel, D. A. Analyst 1994, 119, 719. (e) Unwin, P. R.; Macpherson, J. V. Chem. Ind. 1995, 874. (f) Mirkin, M. V. Anal. Chem. 1996, 177A.
7. Wipf, D. O.; Bard, A. J. J. Electrochem. Soc. 1991, 138, 469.
8. Bard, A. J.; Mirkin, M. V.; Unwin, P. R.; Wipf, D. O. J. Phys. Chem. 1992, 96, 1861.
9. Engstrom, R. C.; Small, B.; Kattan, L. Anal. Chem. 1992, 64, 241.
10. Wipf, D. O.; Bard, A. J. J. Electrochem. Soc. 1991, 138, L4.
11. Mirkin, M. V.; Bulhoes, L. O. S.; Bard, A. J. J. Am. Chem. Soc. 1993, 115, 201.
12. Pierce, D. T.; Unwin, P. R.; Bard, A. J. Anal. Chem. 1992, 64, 1795.
13. Pierce, D. T.; Bard, A. J. Anal. Chem. 1993, 65, 3598.
14. (a) Mandler, D.; Bard, A. J. J. Electrochem. Soc. 1989, 136, 3143.
15. (b) Macpherson, J. V.; Slevin, C. J.; Unwin, P. R. J. Chem. Soc., Faraday Trans. 1996, 92, 3799.
16. (a) Wei, C.; Bard, A. J.; Mirkin, M. V. J. Phys. Chem. 1995, 99, 16033.
17. (b) Solomon, T.; Bard, A. J. J. Phys. Chem. 1995, 99, 17487.
18. (c) Tsionsky, M.; Bard, A. J.; Mirkin, M. V. J. Phys. Chem. 1996, 100, 17881.
19. (d) Shao, Y.; Mirkin, M. V.; Rusling, J. F. J. Phys. Chem. 1997, 101, 3202.
20. (a) Kwak, J.; Anson, F. C. Anal. Chem. 1992, 64, 250.
21. (b) Denuault, G.; Troise Frank, M. H.; Peter, L. M. Faraday Discuss., 1992, 94, 23.
22. (a) Scott, E. R.; White, H. S.; Phipps, J. B. J. Membr. Sci. 1991, 58, 71.
23. (b) Scott, E. R.; White, H. S.; Phipps, J. B. Anal. Chem. 1993, 65, 1537.
24. (c) Scott, E. R.; White, H. S.; Phipps, J. B. Pharm. Res. 1993, 10, 1699.
25. (d) Scott, E. R.; White, H. S.; Phipps, J. B. J. Invest. Dermatol. 1995, 104, 142.
26. (e) Macpherson, J. V.; Beeston, M. A.; Unwin, P. R.; Hughes, N. P.; Littlewood, D. J. Chem. Soc., Faraday Trans. 1995, 91, 1407.
27. (f) Macpherson, J. V.; Beeston, M. A.; Unwin, P. R.; Hughes, N. P.; Littlewood, D. Langmuir 1995, 11, 3959.
28. Slevin, C. J.; Umbers, J. A.; Atherton, J. H.; Unwin, P. R. J. Chem. Soc., Faraday Trans. 1996, 92, 5177.
29. (a) Unwin, P. R.; Bard, A. J. J. Phys. Chem. 1992, 96, 5035.
30. (b) Yang, Y. F.; Denuault, U. J. Electroanal. Chem. 1996, 418, 99.
31. (a) Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. 1994, 98, 1704.
32. (b) Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. 1994, 98, 3109.
33. (c) Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. 1995, 99, 3338.
34. (d) Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. 1995, 99, 14824.
35. (e) Macpherson, J. V.; Unwin, P. R. J. Phys. Chem. 1996, 100, 19475.
36. (f) Macpherson, J. V.; Unwin, P. R.; Hillier, A. C.; Bard, A. J. J. Am. Chem. Soc. 1996, 118, 6445.
37. (a) Mandler, D.; Bard, A. J. J. Electrochem. Soc. 1990, 137, 2468.
38. (b) Mandler, D.; Bard, A. J. Langmuir 1990, 6, 1489.
39. (c) Mandler, D.; Bard, A. J. J. Electrochem. Soc. 1990, 137, 1079.
40. (d) Meltzer, S.; Mandler, D. J. Electrochem. Soc. 1995, 142, L82.
41. (e) Wipf, D. O. Colloids Surf. A 1994, 93, 251.
42. Kwak, J.; Bard, A. J. Anal. Chem. 1989, 61, 1221.
43. Bard, A. J.; Denuault, G.; Friesner, R. A.; Dornblaser, B. C.; Tuckerman, L. S. Anal. Chem. 1991, 63, 1282.
44. Bard, A. J.; Unwin, P. R.; Wipf, D. O.; Zhou, F. Am. Inst. Phys., Conf. Proc. 1992, 241, 235.
45. Martin, R. D.; Unwin, P. R. J. Electroanal. Chem., in press.
46. Unwin, P. R.; Bard, A. J. J. Phys. Chem. 1991, 95, 7814.
47. Zhou, F.; Unwin, P. R.; Bard, A. J. J. Phys. Chem. 1992, 96, 4917.
48. Demaille, C.; Unwin, P. R.; Bard, A. J. J. Phys. Chem. 1996, 100, 14137.
49. Macpherson, J. V.; Unwin, P. R. Anal. Chem. 1997, 69, 2063.
50. (a) Andrieux, C. P.; Hapiot, P.; Savéant, J. M. J. Phys. Chem. 1988, 92, 5992.
51. (b) Andrieux, C. P.; Savéant, J. M. In Investigations of Rates and Mechanisms of Reactions; Bernasconi, C., Ed.; Wiley: New York, 1986; Vol. 6, 4/E, Part 2, p 305.
52. The first studies of liquid/gas interfaces by SECM were reported in the following. Unwin, P. R.; Slevin, C. J. Abstr. - Electrochem. Soc. 1996, 96-2, 810.
53. Saito, Y. Rev. Polarogr. 1968, 15, 177.
54. Peaceman, D. W.; Rachford, H. H. J. Soc. Ind. Appl. Math. 1955, 3, 28.
55. Bard, A. J.; Fan, F.-R. F.; Kwak, J.; Lev, O. Anal. Chem. 1989, 61, 132.
56. (a) Adams, R. N. Electrochemistry at Solid Electrodes; Marcel Dekker: New York, 1969; p 219.
57. (b) Martin, R. D.; Unwin, P. R. Submitted for publication.
58. Seidell, A.; Linke, W. F. Solubilities: Inorganic and Metal-Organic Compounds, 4th ed.; American Chemical Society: Washington, DC, 1958; Vol. 1.
59. (a) Winlove, C. P.; Parker, K. H.; Oxenham, R. K. C. J. Electroanal. Chem. 1984, 170, 293.
60. (b) O'Hare, D.; Winlove, C. P.; Parker, K. H. J. Biomed. Eng. 1991, 13, 304.
61. (c) Denuault, G.; Mirkin, M. V.; Bard, A. J. J. Electroanal. Chem. 1991, 86, 27.
62. Compton, R. G.; Stearn, G. M.; Unwin, P. R.; Barwise, A. J. J. Appl. Electrochem. 1988, 18, 657, and references therein.
63. Griffith, R. O.; McKeown, A; Winn, A. G. Trans. Faraday Soc. 1932, 28, 101.