Formation of adamantane-like structures by reaction of titanocene fluorides with an iminoalane

Angewandte Chemie - International Edition

Volumn 37, Issue 6, 1998, Pages 843-845

  Wessel, Helge ^a   Montero, Mavis L ^a   Rennekamp, Carsten ^a   Roesky, Herbert W ^a   Yu, Peihua ^a   Usón, Isabel ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

Aluminum; Cage compounds; Imido complexes; Metathesis; Titanium

Indexed keywords

EID: 0031924347     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980403)37:6<843::AID-ANIE843>3.0.CO;2-2     Document Type: Article

References (18)

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7. -3.
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17. 19F NMR spectra recorded at room temperature and at 70°C the F atoms are inequivalent, which is attributed to the steric effects of the ligands.
18. [7] All non-hydrogen atoms were refined anisotropically. All hydrogen atoms were included in the refinement in geometrically ideal positions. All disorders were resolved with distance and ADP restraints and refined anisotropically. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100627. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ (fax: (+44)1223-336-033: e-mail: deposit@ccdc.cam.ac.uk).