Synthesis, Structure, and Characterization of the Hydrogen-Substituted Imido Complex TiCl2(NH)(OPPh3)2

Inorganic Chemistry

Volumn 35, Issue 21, 1996, Pages 5968-5969

  McKarns, Peggy J ^a   Yap, Glenn P A ^b   Rheingold, Arnold L ^b   Winter, Charles H ^a  

^a WAYNE STATE UNIVERSITY   (United States)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000848028     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960595s     Document Type: Article

References (38)

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22. Weiller, B. H. Chem. Mater. 1995, 7, 1609. 1994, 6, 260. Dubois, L. H.; Zegarski, B. R.; Girolami, G. S. J. Electrochem. Soc. 1992, 139, 3603. Prybyla, J. A.; Chiang, C.-M.; Dubois, L. H. J. Electrochem. Soc. 1993, 140, 2695. Dubois, L. H. Polyhedron 1994, 13, 1329. Intemann, A.; Koerner, H.; Koch, F. J. Electrochem. Soc. 1993, 140, 3215.
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31. 2Ti: C, 62.63; H, 4.53. Found: C, 61.98; H, 4.30.
32. 1H NMR, and gravimetric analysis of chloride ion) and unidentified, insoluble titanium complexes.
33. -1. The bands that are sensitive to isotope substitution are probably associated with combination stretches involving the imido ligand and with N-H wagging modes: Nakamoto, K. Infrared and Roman Spectra of Inorganic and Coordination Compounds, 4th ed.; Wiley-Interscience: New York, 1986; pp 191-205.
34. -3, R(F) = 8.50% for 2178 observed independent reflections (4° ≤ 2θ ≤ 45°). Carbon and nitrogen atoms were refined isotropically. Hydrogen atoms were refined as idealized contributions. All other atoms were refined anisotropically. Phenyl rings were refined as rigid bodies.
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38. For leading references, see: Yajima, A.; Segawa, Y.; Matsuzaki, R.; Saeki, Y. Bull. Chem. Soc. Jpn. 1983, 56, 2638. Fowles, G. W. A. Prog. Inorg. Chem. 1964, 6, 1. Nicholls, D. Coord. Chem. Rev. 1966, 1, 379.