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note
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In the present experimental configuration, it is possible that some fragments are formed in the ion trap prior to ejection into the drift tube. This type of process should have a negligible effect on fragment ion drift times but could influence the relative abundances of different ions.
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note
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A detailed study of ion mobility distributions recorded by mass-selecting individual m/z ions will be given elsewhere: Liu, Y.; Clemmer, D. E., manuscript in preparation. It is noteworthy that clear evidence of either multiple isomers or multiple conformations are observed for m1z = 545. This is similar to the behavior observed in the cyclodextrin systems (see ref 39).
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