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Volumn 100, Issue 9, 1996, Pages 3652-3664

Theoretical and experimental upper bounds on interfacial charge-transfer rate constants between semiconducting solids and outer-sphere redox couples

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EID: 33748496254     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp951779f     Document Type: Article
Times cited : (56)

References (89)
  • 13
    • 0003297914 scopus 로고
    • Eyring, H., Henderson, D., Yost, W., Eds.; Academic: New York
    • Gerischer, H. In Physical Chemistry: An Advanced Treatise; Eyring, H., Henderson, D., Yost, W., Eds.; Academic: New York, 1970; Vol. 9A, p 463.
    • (1970) Physical Chemistry: An Advanced Treatise , vol.9 A , pp. 463
    • Gerischer, H.1
  • 61
    • 0025383662 scopus 로고
    • In agreement with our work, other investigations on one of the electrodes investigated herein, InP, have also noted a dependence of the impedance behavior on the etchins process (Segar, P. R.; Koval, C. A.; Koel, B. E.; Gebhard, S. C. J. Electrochem. Soc. 1990, 137, 544.).
    • (1990) J. Electrochem. Soc. , vol.137 , pp. 544
    • Segar, P.R.1    Koval, C.A.2    Koel, B.E.3    Gebhard, S.C.4
  • 65
    • 85033035532 scopus 로고    scopus 로고
    • note
    • b value determined for this contact in the dark.
  • 74
    • 85033066363 scopus 로고    scopus 로고
    • note
    • bi. Due to the problems inherent in this system, these values should be viewed as only rough estimates, where the parameters have been chosen to yield the highest rate constant estimates that are consistent with the data.
  • 83
    • 85033049141 scopus 로고    scopus 로고
    • note
    • et for minority carriers above those described herein while not affecting the interfacial rate constant for majority carriers. There appears to date to be neither theoretical nor experimental support for a process in which interfacial electric fields would accelerate the electron into a liquid sufficiently rapidly to produce a significant increase in the capture cross section for ions that are generally at distances in excess of the electron mean free path in the liquid phase.
  • 84
    • 85033040855 scopus 로고    scopus 로고
    • note
    • 89 Coulombic attractions will be minimized in interfacial charge transfer processes by the presence of the electrolyte and the correspondingly small Debye screening lengths in the liquid phase.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.