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Volumn 119, Issue 4, 1997, Pages 756-760

High yield synthesis and characterization of Sn6(μ3-O)4(μ3-OSiMe3)4: A novel main group cluster for the support of multiple transition metal centers

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; ORGANOSILICON DERIVATIVE; TIN DERIVATIVE;

EID: 0031040845     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963450t     Document Type: Article
Times cited : (47)

References (27)
  • 8
    • 25944433926 scopus 로고
    • i: Sasaki, Y.; Miyazawa, N. Kin. Daigaku Rik. Kenk. Hokoku 1992, 28, 237 (Chem. Abstr. 1992, 119, 18173u).
    • (1992) Chem. Abstr. , vol.119
  • 14
    • 0029798282 scopus 로고    scopus 로고
    • The best method for the preparation of 4 in high yield (98%) is via a novel one-step carbon dioxide metathesis route that starts with commerically available bis[bis(trimethylsilyl)amido]tin, see: Sita, L. R., Babcock, J. R.; Xi, R. J. Am. Chem. Soc. 1996, 118, 10912.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 10912
    • Sita, L.R.1    Babcock, J.R.2    Xi, R.3
  • 15
    • 84917846850 scopus 로고
    • 119Sn NMR chemical shift of this material is close to that recorded for 2, -136 and -138 ppm, respectively, see: duMont, W. W.; Grenz, M. Z. Naturforsch. 1983, 38B, 113.
    • (1983) Z. Naturforsch. , vol.38 B , pp. 113
    • DuMont, W.W.1    Grenz, M.2
  • 16
    • 0000591755 scopus 로고
    • and references cited therein
    • 117Sn) coupling satellities between magnetically equivalent tin atoms in a structure, see: Sita, L. R. Adv. Organomet. Chem. 1995, 38, 189 and references cited therein.
    • (1995) Adv. Organomet. Chem. , vol.38 , pp. 189
    • Sita, L.R.1
  • 18
    • 37049113111 scopus 로고
    • The formation of metal oxo clusters via elimination of disiloxane fragments has been observed previously, see: (a) Gaffney, C.; Harrison, P. G.; King, T. J. J. Chem. Soc., Chem. Commun. 1980, 1251. (b) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663 and references cited therein.
    • (1980) J. Chem. Soc., Chem. Commun. , pp. 1251
    • Gaffney, C.1    Harrison, P.G.2    King, T.J.3
  • 19
    • 37049113111 scopus 로고
    • and references cited therein
    • The formation of metal oxo clusters via elimination of disiloxane fragments has been observed previously, see: (a) Gaffney, C.; Harrison, P. G.; King, T. J. J. Chem. Soc., Chem. Commun. 1980, 1251. (b) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663 and references cited therein.
    • (1987) New J. Chem. , vol.11 , pp. 663
    • Hubert-Pfalzgraf, L.G.1
  • 23
    • 1842299007 scopus 로고    scopus 로고
    • note
    • 4(L)] TBP complexes should have four IR-active v(CO)'s.
  • 24
    • 0000219605 scopus 로고
    • and references cited therein
    • 4L complexes where equatorial-axial interconversions do occur, see: Martin, L. R.; Einstein, F. W. B.; Pomeroy, R. K. Inorg. Chem. 1985, 24, 2777 and references cited therein.
    • (1985) Inorg. Chem. , vol.24 , pp. 2777
    • Martin, L.R.1    Einstein, F.W.B.2    Pomeroy, R.K.3
  • 25
    • 0345936372 scopus 로고
    • A similar umbrella effect has been noticed in the solid-state structures of several other tin-transition metal carbonyl complexes, see: (a) Bryan, R. F. J. Chem. Soc. A 1968, 696. (b) Weidenbruch, M.; Stilter, A.; Peters, K.; v. Schnering, H. G. Z. Anorg. Allg. Chem. 1996, 622, 534.
    • (1968) J. Chem. Soc. A , pp. 696
    • Bryan, R.F.1
  • 26
    • 0000670081 scopus 로고    scopus 로고
    • A similar umbrella effect has been noticed in the solid-state structures of several other tin-transition metal carbonyl complexes, see: (a) Bryan, R. F. J. Chem. Soc. A 1968, 696. (b) Weidenbruch, M.; Stilter, A.; Peters, K.; v. Schnering, H. G. Z. Anorg. Allg. Chem. 1996, 622, 534.
    • (1996) Z. Anorg. Allg. Chem. , vol.622 , pp. 534
    • Weidenbruch, M.1    Stilter, A.2    Peters, K.3    V. Schnering, H.G.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.