Solid-state diode-like chemiluminescence based on serial, immobilized concentration gradients in mixed-valent poly[Ru(vbpy)3](PF6)2 films

Journal of the American Chemical Society

Volumn 118, Issue 43, 1996, Pages 10609-10616

  Maness, Karolyn M ^a,b   Terrill, Roger H ^a,c   Meyer, Thomas J ^a   Murray, Royce W ^a   Wightman, R Mark ^a  

^a The University of North Carolina at Chapel Hill   (United States)

^b PFIZER INC   (United States)

^c UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

RUTHENIUM COMPLEX;

ARTICLE; CHEMOLUMINESCENCE;

EID: 0029799817     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953185w     Document Type: Article

References (77)

1. Pickup, P. G.; Murray, R. W. J. Am. Chem. Soc. 1983, 105, 4510-4514.
2. Pickup, P. G.; Kutner, W.; Leidner, C. R.; Murray, R. W. J. Am. Chem. Soc. 1984, 106, 1991-1998.
3. Jernigan, J. C.; Chidsey, C. E. D.; Murray, R. W. J. Am. Chem. Soc. 1985, 107, 2824-2826.
4. Chidsey, C. E.; Feldman, B. J.; Lundgren, C.; Murray, R. W. Anal. Chem. 1986, 58, 601-607.
5. Chidsey, C. E. D.; Murray, R. W. Science 1986, 231, 25-31.
6. Jernigan, J. C.; Murray, R. W. J. Am. Chem. Soc. 1987, 109, 1738-1745.
7. Jernigan, J. C.; Murray, R. W. J. Phys. Chem. 1987, 91, 2030-2032.
8. Jernigan, J. C.; Surridge, N. A.; Zvanut, M. E.; Silver, M.; Murray, R. W. J. Phys. Chem. 1989, 93, 4620-4627.
9. Dalton, E. F.; Surridge, N. A.; Jernigan, J. C.; Wilbourn, K. O.; Facci, J. S.; Murray, R. W. Chem. Phys. 1990, 141, 143-157
10. Surridge, N. A.; Zvanut, M. E.; Keene, F. R.; Sosnoff, C. S.; Silver, M.; Murray, R. W. J. Phys. Chem. 1992, 96, 962-970.
11. Sullivan, M. G.; Murray, R. W. J. Phys. Chem. 1994, 98, 4343-4351.
12. Abruna, H. D. Electroresponsive Molecular and Polymeric Systems; Skotheim, T., Ed.; Marcell Dekker: New York, 1988; pp 97-171.
13. Abruna, H. D.; Bard, A. J. J. Am. Chem. Soc. 1982, 104, 2611-2642.
14. Denisevich, P.; Willman, K. W.; Murray, R. W. J. Am. Chem. Soc. 1981, 103, 4727-4737.
15. Abruna, H. D.; Denisevich, P.; Umana, M.; Meyer, T. J.; Murray, R. W. J. Am. Chem. Soc. 1981, 103, 1-5.
16. Pickup, P. G.; Murray, R. W. J. Electrochem. Soc. 1984, 131, 833-839.
17. Kittlesen, G. P.; White, H. S.; Wrighton, M. S. J. Am. Chem. Soc. 1984, 106, 7389-7396.
18. Paul, E. W.; Ricco, A. J.; Wrighton, M. S. J. Phys. Chem. 1985, 89, 1441-1447.
19. Faulkner, L. R. Int. Rev. Sci., Phys. Chem. Ser. Two 1975, 9, 213-263.
20. Faulkner, L. R.; Bard, A. J. Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1977; Vol. 10, pp 1-95.
21. Faulkner, L. R. Methods Enzymol. 1978, 57, 494-526.
22. Park, S.; Tryk, D. A. Rev. Chem. Intermed. 1981, 4, 43-79.
23. Faulkner, L. R.; Glass, R. S. Chemical and Biological Generation of Excited States; Adam, W., Cilento, G.; Academic Press: New York, 1982; pp 191-227.
24. Gundermann, K. D.; McCapra, F. Chemiluminescence in Organic Chemistry; Gundermann, K. D., McCapra, F., Eds.; Springer-Verlag: New York, 1987: pp 130-147.
25. Knight, A. W.; Greenway, G. M. Analyst 1994, 119, 879-890.
26. Rubinstein, I.; Bard, A. J. J. Am. Chem. Soc. 1981, 103, 5007-5013.
27. Fan, F.-R. F.; Mau, A.; Bard, A. J. Chem. Phys. Lett. 1985, 116, 400-404.
28. Abruna, H. D. J. Electrochem. Soc. 1985, 132, 842-849.
29. Zhang, X.; Bard, A. J. J. Phys. Chem. 1988, 92, 5566-5569.
30. Miller, C. J.; McCord, P. Langmuir 1991, 7, 2781-2787.
31. Obeng, Y. S.; Bard, A. J. Langmuir 1991, 7, 195-201.
32. Xu, X.; Bard, A. J. Langmuir 1994, 10, 2409-2414.
33. Richter, M. M.; Fan, F. F.; Klavetter, F.; Heeger, A. J.; Bard, A. J. Chem. Phys. Lett. 1994, 226, 115-120.
34. Reference deleted in press.
35. Terrill, R. G.; Sheehan, P. E.; Long, V. C.; Washburn, S.; Murray, R. W. J. Phys. Chem. 1994, 98, 5127-5134.
36. Terrill, R. H.; Hatazawa, T.; Murray, R. W. Electron Transport and Frozen Concentration Gradients in a Mixed Valent, Viologen Molten Salt. J. Phys. Chem. Accepted for publication.
37. Terrill, R. H.; Hutchenson, J. E.; Murray, R. W. Frozen Concentration Gradients and Solid State Electron Hopping Transport in a Novel Viologen-Tetraethylene Oxide Copolymer. Manuscript in preparation.
38. Burroughes, J. H.; Bradley, D. D. C.; Brown, A. R.; Marks, R. N.; Mackay, K.; Friend, R. H. ; Burns, P. L.; Holmes, A. B. Nature 1990, 347, 539-541.
39. Gustafsson, G.; Cao, Y.; Treacy, G. M.; Klavetter, F.; Colaneri, N.; Heeger, A. J. Nature 1992, 357, 477-479.
40. Burn, P. L.; Kraft, A.; Baigent, D. R.; Bradley, D. D. C.; Brown, A. R.; Friend, R. H.; Gymer, R. W.; Holmes, A. B.; Jackson, R. W. J. Am. Chem. Soc. 1993, 115, 10117-10124.
41. Greenham, N. C.; Moratti S. C.; Bradley, D. C.; Friend, R. H.; Holmes, A. B. Nature 1993, 565, 628-630.
42. Berggren, M.; Inganas, O.; Gustafsson, G.; Rasmusson, J.; Andersson, M. R.; Hjertberg, T.; Wennerstrom, O. Nature 1994, 372, 444-446.
43. Granstrom, M.; Berggren, M.; Inganas, Olle Science 1995, 267, 1479-1481.
44. Kido, J.; Kimura, M.; Nagai, K. Science 1995, 267, 1332-1334.
45. Parker, I. D. J. Appl. Phys. 1994, 75, 1656-1666.
46. Denisevich, P.; Abruna, H. D.; Leidner, C. R.; Meyer, T. J.; Murray, R. W. Inorg. Chem. 1982, 21, 2153-2161.
47. McCarley, R. L.; Thomas, R. E.; Irene, E. A.; Murray, R. W. J. Electrochem. Soc. 1990, 137, 1485-1490.
48. Maness, K. M.; Bartelt, J. E.; Wightman, R. M. J. Phys. Chem. 1994, 98, 3993-3998.
49. These formal potentials were determined prior to applying the potential steps from the average of the anodic and cathodic voltammetric peak potentials obtained at a scan rate of 100 mV/s.
50. The minima observed in the current is likely the result of a change in polymer conductance during electrolysis. This change arises from the necessary rearrangement of counterions during the course of establishing the concentration gradients illustrated in Figure 1.
51. Amatore, C.; Fosset, B.; Maness, K. M.; Wightman, R. M. Anal. Chem. 1993, 65, 2311-2316.
52. Luttmer, J. D.; Bard, A. J. J. Phys. Chem. 1981, 85, 1155-1159.
53. Glass, R. S.; Faulkner, L. R. J. Phys. Chem. 1981, 85, 1160-1165.
54. Wallace, W. L.; Bard, A. J. J. Phys. Chem. 1979, 83, 1350-1357.
55. Gould, S.; Guadalope, A.; Meyer, T. J. Unpublished results.
56. Ghosh, P. K.; Bard, A. J. J. Electroanal. Chem. 1984, 169, 113-128.
57. Surridge, N. A.; Jemigan, J. C.; Dalton, E. F.; Buck, R. P.; Watanabe, M.; Zhang, H.; Pinkerton, M.; Wooster, T. T.; Longmire, M. L.; Facci, J. S.; Murray, R. W. Faraday Discuss. Chem. Soc. 1989, 88, 1-17.
58. Majda, Marcin Molecular Design of Electrode Surfaces; Murray, R. W., Ed.; John Wiley & Sons, Inc.: New York, 1992; pp 159-206.
59. +1 species.
60. Waldeck, D. H.; Alivisatos, A. P.; Harris, C. B. Surf. Sci. 1985, 158, 103-115.
61. Chance, R. R.; Prock, A.; Silbey, R. J. Chem. Phys. 1974, 60, 2744-2748.
62. Chance, R. R.; Miller, A. H.; Prock, A.; Silbey, R. Chem. Phys. Lett. 1975, 33, 590-592.
63. Kuhn, H. J. Chem. Phys. 1970, 53, 101-108.
64. Chance, R. R.; Prock, A.; Silbey, R. Adv. Chem. Phys. 1978, 37, 1-65.
65. Feldman, B. J.; Feldberg, S. W.; Murray, R. W. J. Phys. Chem. 1987, 91, 6558-6560.
66. Cammarata, V.; Talham, D. R.; Crooks, R. M.; Wrighton, M. S. J. Phys. Chem. 1990, 94, 2680-2684.
67. Licht, S.; Cammarat, V.; Wrighton, M. S. J. Phys. Chem. 1990, 94, 6133-6140.
68. f are the number of fingers.
69. 2+ film containing no valence state concentration gradients very little current and no emission was observed.
70. Itoh, K.; Honda, K. Chem. Lett. 1979, 99-102.
71. Van Houten, J.; Watts, R. J. J. Am. Chem. Soc. 1976, 98, 4853-4858.
72. The elevation of conductance appearing at the beginning of the second sweep series may be an artifact of the 26-min interval between these experiments, during which time 2 potential steps (duration, 1 and 5 s; ±5 V around 2.6 V) and 3 potential sweeps (±25 V around 2.6 V; 100 V/s) were performed.
73. 3+ in the film is sufficiently fast as to not limit the overall charge transport rate through the film.
74. 2+ film at 300 mV /s.
75. Pei, Q.; Yu, G.; Zhang, C.; Yang, Y.; Heeger, A. J. Science 1995, 269, 1086-1088. Pei, Q.; Yang, Y.; Yu, G.; Zhang, C.; Heeger, A. J. J. Am. Chem. Soc. 1996, 118, 3922-3929.
76. Pei, Q.; Yu, G.; Zhang, C.; Yang, Y.; Heeger, A. J. Science 1995, 269, 1086-1088. Pei, Q.; Yang, Y.; Yu, G.; Zhang, C.; Heeger, A. J. J. Am. Chem. Soc. 1996, 118, 3922-3929.
77. 2°s) for an applied voltage of 2.6 V. This estimate was made through a consideration of the film conductivity at 0 °C as obtained from Figure 5, along with the ECL efficiency and the total surface area of the IDA electrode (both gaps and fingers).