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Volumn 119, Issue 8, 1997, Pages 1997-2005

Electron and mass transport in hybrid redox polyether melts: Co and Fe bipyridines with attached polyether chains

Author keywords

[No Author keywords available]

Indexed keywords

BIPYRIDINE DERIVATIVE; POLYETHER;

EID: 0030887197     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962531m     Document Type: Article
Times cited : (94)

References (72)
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    • note
    • 1/2. The data were analyzed using both eq 2 and the Cottrell equation in order to consistently check for mixed diffusion geometries. The reported D is the average of these.
  • 39
    • 1842399837 scopus 로고    scopus 로고
    • note
    • EX is orders of magnitude smaller in the metal complex melts than in aqueous solution.
  • 41
    • 1842402044 scopus 로고    scopus 로고
    • note
    • Voltammetry of the MePEG-750 tailed complex was irreproducible and is not shown.
  • 42
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    • note
    • 3a owing to the use of a supporting electrolyte there.
  • 45
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    • note
    • f is estimated to be 12 Å. While the use of C in the calculation approximates the excluded volume for the chain, this method neglects the bond angle restrictions on the conformation of the chain.
  • 52
    • 1842284282 scopus 로고    scopus 로고
    • note
    • 22d as 0.8 Å.
  • 54
    • 1842316722 scopus 로고    scopus 로고
    • note
    • -1 for the Fe(III/II) reaction. These large coupling terms are more consistent with adiabatic than non-adiabatic behavior.
  • 55
    • 1842312904 scopus 로고    scopus 로고
    • note
    • S = 9.16.
  • 56
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    • University of North Carolina at Chapel Hill, manuscript in preparation
    • Masui, H., University of North Carolina at Chapel Hill, manuscript in preparation.
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    • note
    • 2d-f and that the experimental activation energy includes that for the attached polyether chain reorientation (i.e., the thermal barrier of dipolar longitudinal relaxation of the attached chains).
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    • In ref 32a, pp 227
    • (b) In ref 32a, pp 227.
  • 68
    • 1842315706 scopus 로고    scopus 로고
    • note
    • c = -1 for Co(II/I).
  • 70
    • 1842393013 scopus 로고    scopus 로고
    • 2+ r = 7 Å
    • 2+ r = 7 Å.
  • 71
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    • note
    • -1, respectively.
  • 72
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    • note
    • 4.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.