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Volumn 118, Issue 29, 1996, Pages 7010-7011

Directly-observed β-hydrogen elimination of a late transition metal amido complex and unusual fate of imine byproducts

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; IMINE;

EID: 0030015257     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja961439n     Document Type: Article
Times cited : (69)

References (28)
  • 3
    • 0001687271 scopus 로고
    • Reversible imine insertion into a dimeric rhodium hydride has been observed, and therefore partial β-hydrogen elimination of an isolated dimeric amide has been observed: Fryzuk, M. D.; Piers, W. E. Organometallics 1990, 9, 986.
    • (1990) Organometallics , vol.9 , pp. 986
    • Fryzuk, M.D.1    Piers, W.E.2
  • 5
    • 84982060260 scopus 로고
    • Examples of a nickel dimethylamido complex were prepared over 20 years ago: Klein, H. F.; Karsch, H. H. Chem. Ber. 1973, 106, 2438.
    • (1973) Chem. Ber. , vol.106 , pp. 2438
    • Klein, H.F.1    Karsch, H.H.2
  • 10
    • 0000736411 scopus 로고
    • An example of β-elimination from an alkoxide has been observed directly: Blum, O.; Milstein, D. J. Am. Chem. Soc. 1995, 117, 4582.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 4582
    • Blum, O.1    Milstein, D.2
  • 11
    • 0000041989 scopus 로고
    • For a recent review see: James, B. R. Chem. Ind. 1995, 62, 167.
    • (1995) Chem. Ind. , vol.62 , pp. 167
    • James, B.R.1
  • 12
    • 0000918807 scopus 로고
    • Hartley, S. P. F. R., Ed.; John Wiley: New York
    • Cross, R. J. In The Chemistry of the Metal-Carbon Bond; Hartley, S. P. F. R., Ed.; John Wiley: New York, 1985; Vol. 2, p 559.
    • (1985) The Chemistry of the Metal-Carbon Bond , vol.2 , pp. 559
    • Cross, R.J.1
  • 13
    • 0001080640 scopus 로고
    • Reaction of t-BuNHLi with Vaska's complex does not give monomeric amido complexes similar to 1-3, while a mixture of monomeric and dimeric products was obtained from reaction of t-BuNHLi with the triethylphosphine version of Vaska's complex: Rahim, M.; Bushweller, C. H.; Ahmed, K. J. Organometallics 1994, 13, 4952.
    • (1994) Organometallics , vol.13 , pp. 4952
    • Rahim, M.1    Bushweller, C.H.2    Ahmed, K.J.3
  • 16
    • 8944223238 scopus 로고    scopus 로고
    • note
    • 2H NMR spectrometry. The amount of deterium in the hydride position was time-dependent, as it eventually washed completely into the phosphine ligand.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.