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xO layer in air or by absorption of airborne contaminants. However, imaging the Ag films under potential control greately enhances the resolution. Near atomic resolution was obtained for the Ag films in 0.1 M Naf solutions at potentials between -1.30 and -0.30 V vs Ag/AgCl.
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-1) should be used to determine the apparent RF. Analysis of larger STM images understimate the RF since the local topography has been undersampled.
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The RF for a polycrystalline Ag disk was found to increase from ca. 1.3 to 2.5 after 15 oxidation - reduction cycles in 0.1 M KCl.
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Transport of an ion through the interfacial field contributes a fractional charge, gz, to the electrosorption valency, where g represents a normalized relative distance within the Helmholtz layer and z is the ion charge (-1 for ethanethiolate). See discussion in ref 39.
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66
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1842398960
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μj≠i = γF and leads to a sign error in the numerical value of γ. See ref 39 for a more thorough discussion of these relationships.
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